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  • 1990-1994  (4)
  • 1985-1989
  • Analytical Chemistry and Spectroscopy  (3)
  • Incompressible flows  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 23 (1994), S. 406-416 
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This study shows that fast atom bombardment (FAB) in combination with collisional activation and tandem mass spectrometric techniques is useful for the characterization of, and the differentiation between, O-diglycosyl, O-C- diglycosyl, and di-C-glycosyl flavonoids. A quick differentiation between the three types of glycosyl flavonoids is possible by simply examining FAB mass spectra. Low-energy product ion spectra of [M + H] + ions have been used for determining the carbohydrate sequence in O-diglycosyl flavonoids and characterizing the terminal mono-saccharide in O-C-diglycosyl flavonoids. The data obtained for per-O- deuterated precursor ion species of O-diglycosyl flavonoids indicate that O-linked hydrogen atoms are involved in the formation of Yn + ions. High-energy product ion spectra of [M + H] + ions enable further characterization and differentiation of isomeric di-6,8-C-glycosides.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 21 (1992), S. 213-221 
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The present study deals with the use of liquid secondary ion mass spectrometry in combination with collisionally activated dissociation and linked scanning at constant B/E for differentiation and structural analysis of 6-C- and 8-C-glycosidic flavonoids in the positive ion mode. Flavonoids of mono-C-glycosidic nature were investigated. Special emphasis is given to the rationalization of fragment ions which allow differentiation between isomers.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 21 (1992), S. 408-410 
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 17 (1993), S. 271-289 
    ISSN: 0271-2091
    Keywords: Least-squares finite element method ; Time-dependent ; Incompressible flows ; Bqussinesq approximation ; Navier-Stokes equations ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The time-dependent Navier-Stokes equations and the energy balance equation for an incompressible, constant property fluid in the Boussinesq approximation are solved by a least-squares finite element method based on a velocity-pressure-vorticity-temperature-heat-flux (u-P-ω-T-q) formulation discretized by backward finite differencing in time. The discretization scheme leads to the minimization of the residual in the l2-norm for each time step. Isoparametric bilinear quadrilateral elements and reduced integration are employed. Three examples, thermally driven cavity flow at Rayleigh numbers up to 106, lid-driven cavity flow at Reynolds numbers up to 104 and flow over a square obstacle at Reynolds number 200, are presented to validate the method.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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