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  • 1
    ISSN: 1572-879X
    Keywords: methanol synthesis ; Cu/ZnO catalyst ; Cu-Zn alloy ; effect of reduction temperature
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The behavior and role of ZnO in Cu/ZnO catalysts for the hydrogenations of CO and CO2 were studied using XRD, TEM coupled with EDX, TPD and FT-IR. As the reduction temperature increased, the specific activity for the hydrogenation of CO2 increased, whereas the activity for the hydrogenation of CO decreased. The EDX and XRD results definitely showed that ZnO x (x = 0–1) moieties migrate onto the Cu surface and dissolve into the Cu particle forming a Cu-Zn alloy when the Cu/ZnO catalysts were reduced at high temperatures above 600 K. The content of Zn dissolved in the Cu particles increased with reduction temperature and reached ∼ 18% at a reduction temperature of 723 K. The CO-TPD and FT-IR results suggested the presence of Cu+ sites formed in the vicinity of ZnO x on the Cu surface, where the Cu+ species were regarded as an active catalytic component for methanol synthesis.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0935-6304
    Keywords: Supercritical fluid chromatography, SFC ; Chiral stationary phase, CSP ; Optical resolution ; α-Amino acid derivatives ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 43 (1991), S. 767-773 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Based on the Mueller matrix approach, we have successfully designed and constructed a highly sensitive instrument for measuring optical birefringence (LB) by using a polarization modulation method and phase-sensitive technique. Our instrument can measure the retardation of a sample up to 10-2 radian. Using this instrument, we have measured the residual birefringence of thermosetting resins, CR-39 resin and epoxy resin, for opticaldisk substrates. CR-39 resin results are summarized as follows: (1) Annealing is very effective in reducing LB of samples; (2) samples prepared from raw material 2 (monomer purity, 96%, oligomer, 4%) have smaller LB than those from raw material 1 (monomer purity, 99.9%); and (3) annealed samples prepared from 2 satisfy the requirement on LB to be used as optical-disk substrates. For epoxy resin: (1) “Second curing” largely reduces LB of samples; (2) “slow cooling” is more effective in reducing LB of samples than “fast cooling;” (3) after the second curing, cutting does not induce any residual stress birefringence in samples; and (4) slow-cooled samples have good optical properties to be used as optical disk substrates.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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