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  • 1990-1994  (2)
  • Alkylammonium-alkanol-intercalates  (1)
  • Newtonblackfilms  (1)
  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Colloid & polymer science 268 (1990), S. 760-765 
    ISSN: 1435-1536
    Schlagwort(e): X-rayinvestigations ; commonblackfilms ; Newtonblackfilms ; stratifiedfilms ; foamfilms
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Notizen: Abstract The x-ray scattering by the three types of black foam films (common black, Newton black, and stratified black films) was experimentally studied. A special device in which flat black films with an area of ca. 2 cm2 can be produced was developed and x-ray diffraction patterns were obtained by a vertical diffractometer. The three types of films differ significantly in their x-ray reflections, which proves that they have different structure. For common black films, the comparison of observed and calculated intensities lead to a model, which corresponds to the three-layer model. The Newton black films exhibit diffraction trace with only one highly asymetric peak and there is, as of yet, no unambigous interpretation. The patterns of the stratified black films have several pronounced sharp peaks corresponding to the areas of different films with a given thickness.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Colloid & polymer science 271 (1993), S. 891-900 
    ISSN: 1435-1536
    Schlagwort(e): Alkylammonium-alkanol-intercalates ; miscibility gap in alkanol complexes ; structure of alkyl interlayers ; coexistence of phases
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Notizen: Abstract Measurements of basal spacings ofn-tetradecylammonium-n-tetradecanol complexes of beidellite and montmorillonite in a wide range of tetradecanol concentrations have been carried out. Three different intercalate phases have been established at room temperature. In definite concentration ranges two of the phases coexist. These miscibility gaps disappear when the temperature is increased above 80°C. They appear again at cooling. This reversibility with temperature confirms the equilibrium nature of the phases observed. Additional information about the structure of the phases has been obtained by basal spacing measurements at constant temperature and alkanol concentration with all nine members of then-alkyl homologs with 10 to 18 carbon atoms in the chains. The structures of the interlayers in the different phases have been discussed.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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