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Digitale Medien

Synthesis and structural characterization of the hydrido carbido ruthenium cluster [PPh4][Ru6C(CO)16H] (1992)

Chihara, Teiji ; Yamazaki, Hiroshi

Springer

Journal of cluster science 3 (1992), S. 489-497

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ISSN: 1572-8862

Schlagwort(e): Hydrido cluster ; ruthenium cluster ; interstitial carbido ligand ; crystallographic structure ; monoanionic cluster

Quelle: Springer Online Journal Archives 1860-2000

Thema: Maschinenbau , Physik

Notizen: Abstract According to the protonation of [PPh4]2[Ru6C(CO)16] (1b) withp-toluene-sulfonic acid, a hydrido ruthenium cluster [PPh4][Ru6C(CO)16H] (3b) was obtained in 53% yield, which readily decomposed in protic solvents even at −20°C to yield1b, Ru6C(CO)16H2, and Ru5C(CO)15. Cluster3b was characterized by single-crystal X-ray analysis. The six metal atoms are arranged in the form of an octahedron with the carbido ligand located in the center. There are 13 terminal carbonyl, three bridging carbonyl, and a bridging hydrido ligands.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF00702754

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Digitale Medien

Fluorescencein situ hybridization analysis of chromosomal localization of three human cytochrome P450 2C genes (CYP2C8, 2C9, and 2C10) at 10q24.1 (1994)

Inoue, Kiyoshi ; Inazawa, Johji ; Suzuki, Yasuhiko ; [weitere]

Springer

Journal of human genetics 39 (1994), S. 337-343

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ISSN: 1435-232X

Schlagwort(e): fluorescencein situ hybridization ; CYP2C subfamily ; chromosome 10 ; chromosomal localization ; polymerase chain reaction

Quelle: Springer Online Journal Archives 1860-2000

Thema: Biologie , Medizin

Notizen: Summary Chromosomal localization of three human cytochrome P450 genes belonging to the CYP2C subfamily (CYP2C8, 2C9, and 2C10) was identified by fluorescencein situ hybridization (FISH). An original MP-8 clone was used as a DNA probe for the assignment of the CYP2C10 gene, while two cDNA probes, a 1.37 kb fragment of CYP2C8 and a 1.19 kb fragment (MP-20 and MP-4 clones, respectively) by polymerase chain reaction using a single human liver cDNA library. The results showed that three human CYP2C8, 2C9, and 2C10 cDNAs were located at the same subchromosomal region, 10q24.1.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF01874052

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