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  • 1990-1994  (1)
  • Chemistry  (1)
  • vanadium phosphates
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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 590 (1990), S. 213-221 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Influence of Mechanical Activation on Thermal Decomposition of GibbsiteThe influence of mechanical activation on structure and reactivity of gibbsite in dependence on stress mechanism (pressure stress and shearing in vibration-mills, shock stress in disintegrators) is investigated. With increasing mechanical treatment the degree of order is decreased. Mechanically disturbed gibbsite shows changed decomposition series. After mechanical activation and short-time heating there are formed nearly X-ray amorphous Al2O3 with high spec. surfaces. It is possible to transform these alumina into pseudo-boehmite with a very low alkali content. The transformation into pseudo-boehmite is dependent on the degree of order of the mechanically pretreated gibbsite and is independent of the spec. surface of X-ray amorphous Al2O3. The products can be used for the preparation of adsorbents and catalyser components.
    Notes: Die mechanische Aktivierung von Hydrargillit in Abhängigkeit vom Beanspruchungsmechanismus (Druck- und Scherbeanspruchung in Schwingmühlen, Prallbeanspruchung in Desintegratoren) wird untersucht. Der gestörte Hydrargillit zeigt ein verändertes thermisches Abbauverhalten. Durch die mechanische Aktivierung und anschließende Kurzzeit-Erhitzung entstehen oberflächenreiche röntgenamorphe Aluminiumoxide, die durch H2O in Pseudoböhmit umgesetzt werden in Abhängigkeit vom Störungsgrad des mechanisch behandelten Hydrargillits und nicht von der spezifischen Oberfläche des röntgenamorphen Aluminiumoxids. Die entstehenden böhmitreichen Produkte haben einen geringen Na2O-Gehalt und können z. B. zur Herstellung von Adsorbentien und Katalysatorkomponenten verwendet werden.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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