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  • 1990-1994  (2)
  • Engineering  (1)
  • Polymer and Materials Science  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 30 (1992), S. 851-863 
    ISSN: 0887-624X
    Keywords: polymerization ; kinetics ; free radical ; transfer ; photolysis ; propagation ; rate coefficients ; termination ; EPR ; copolymerization ; initiation ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The problems of determining reliable, well-characterized values of kinetic parameters in free-radical polymerizations are discussed. The origins of the fact that experimental determinations of rate coefficients of ostensibly identical systems often result in quite different values being reported can be ascribed to subtle mechanistic assumptions made in data interpretation, which are considered in detail. A series of recommendations to assist in overcoming these problems, and to highlight their origins, are presented, with emphasis placed on new techniques including those employing laser photolysis and EPR.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 17 (1993), S. 463-475 
    ISSN: 0271-2091
    Keywords: Finite elements ; Streamline upwind ; Quadratic elements ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A direct streamline upwind method has been developed for convection-dominated flow problems utilizing quadratic elements. The approach presented retains the curve-sidedness feature offered by these elements. This facilitates the use of boundary conforming elements in domains that possess extreme curvature such as turbomachinery bladed components, for which the method is particularly suited. Three test cases are solved to evaluate the stability and diffusive characteristics of the numerical solution. The results presented clearly demonstrate that the proposed method does not exhibit any non-physical spatial oscillations, nor does it suffer from the traditional problem of excessive numerical diffusion.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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