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  • 1990-1994  (12)
  • Polymer and Materials Science  (10)
  • Organic Chemistry  (1)
  • endurance exercise  (1)
  • Industrial Chemistry
  • 1
    ISSN: 1436-6215
    Keywords: Ausdauerbelastung ; Sportgetränke ; Kohlenhydrataufnahme ; Energieumsatz ; Stoffwechsel ; “post-exercise ketosis” ; endurance exercise ; sports beverages ; carbohydrate consumption ; energy turnover ; metabolism ; post-exercise ketosis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Medicine
    Description / Table of Contents: Summary The present study addressed the effects of carbohydrate consumption during endurance exercise on performance, energy turnover, and metabolism. Well-trained endurance runners consumed a beverage with (cho[+]) or without (cho[−]) carbohydrates during a long-distance run (46.6 km). The respiratory quotient (RQ), plasma levels of carbohydrate and fat metabolites, and of hormones (insulin, glucagon) were measured before, several times during, and after the run. The mean running speed for the entire distance was 13.6 and 13.4 km/h with the cho[+] and cho[−] beverage, respectively. The decrease in speed that was observed towards the end of the run was somewhat more pronounced with consumption of the cho[−] beverage. The RQ decreased during the run almost linearily. This decrease was independent of the consumed beverage. The changes in plasma levels of lactate, free fatty acids (FFA), glycerol, D-3-hydroxybutyrate (DHB), glucagon and insulin that occurred during the run were not affected by intake of the cho[+] beverage. However, intake of the cho [+] beverage prevented the decrease in plasma glucose observed towards the end of the run under control conditions, and eliminated the steep postexercise increase in plasma DHB. The intake of the cho[+] beverage also caused a rapid decrease in plasma levels of FFA and glucagon after the run, and slightly increased plasma insulin. The results demonstrate that ingestion of a carbohydrate-containing beverage during a long-distance run affects metabolism only during the final phase of the run and during the subsequent recovery period. Moreover, carbohydrate consumption improves performance only during the final phase of a long-distance run.
    Notes: Zusammenfassung In der vorliegenden Studie wurde der Einfluß der Kohlenhydrataufnahme während eines Langstreckenlaufes über 46,6 km auf Leistungsfähigkeit, Energieumsatz und Stoffwechsel untersucht. Gut trainierte Läufer erhielten während des Laufes entweder ein kohlenhydrathaltiges (KH[+]) oder ein kohlenhydratfreies (KH[−]) Getränk. Der respiratorische Quotient (RQ), die Plasmakonzentrationen von Metaboliten des Kohlenhydrat- bzw. Fettstoffwechsels und von Hormonen (Insulin, Glucagon) wurden gemessen. Die mittlere Geschwindigkeit über die gesamte Distanz betrug 13,6 (KH[+]) bzw. 13,4 (KH[−]) km/h. Dabei war der gegen Ende des Laufes allgemein feststellbare Leistungsabfall bei Aufnahme des KH[+]-Getränkes etwas schwächer ausgeprägt als bei Aufnahme des KH[−]-Getränkes. Der RQ nahm unabhängig von der Kohlenhydrataufnahme während des gesamten Laufes annähernd linear ab. Die während des Laufes feststellbaren Veränderungen der Plasmakonzentrationen von Lactat, Freien Fettsäuren (FFS), Glycerin, D-3-Hydroxybutyrat (DHB), Glucagon und Insulin wurden durch die Kohlenhydrataufnahme nicht signifikant beeinflußt. Die Aufnahme des KH[+]-Getränkes verhinderte jedoch den unter Kontrollbedingungen gegen Ende des Laufes feststellbaren Abfall der Plasmaglucosekonzentration sowie den steilen Anstieg des Plasmaspiegels von DHB nach dem Lauf. Ferner führte die Kohlenhydrataufnahme zu einem raschen Abfall der Plasmakonzentrationen von FFS und Glucagon nach dem Lauf und erhöhte die Plasmakonzentration von Insulin geringfügig. Die Ergebnisse zeigen, daß die exogene Zufuhr von Kohlenhydraten den Stoffwechsel erst in der Endphase eines Langstreckenlaufes sowie in der anschließenden Erholungsphase beeinflußt. Ein positiver Effekt der Kohlenhydrataufnahme auf die Leistungsfähigkeit tritt ebenfalls erst in der Endphase eines so langen Laufes auf.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: HNBR rubbers, which are made by selective hydrogenation of the olefinic bonds of NBR rubbers, have been developed, because they show improved resistance towards heat and chemicals. In this study, two other properties are discussed that arise from the fact that HNBR rubbers are fairly alternating copolymers of unpolar butylene and polar acrylonitrile units: At intermediate compostions, HNBR rubbers form homogeneous blends with PVC, and near the symmetric composition they exhibit strain-induced crystallisation. The thermal transitions of the HNBR rubbers and their miscibility with PVC were analyzed, as well as the crystallisation and the stress-strain behaviour of a HNBR of symmetric composition.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 199 (1992), S. 191-205 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Gesättigte aliphatische Polyester mit dem aus Stärke erhältlichen 1.4:3.6-Dianhydrosorbit wurden mit PVC gemischt. Die mechanischen Eigenschaften dieser Mischungen wurden mittels Differentialkalorimetrie, Spannungs-Dehnungs-Experimenten und Torsionspendelmessungen untersucht. Polyester mit mehr als vier Methylengruppen in der Säurekomponente sind mit PVC mischbar. Mischungen aus PVC und Poly(1.4:3.6-dianhydrosorbitadipat) sind dagegen unverträglich; sie zeigen für jedes Mischungsverhältnis zwei Glastemperaturen, die bei denen der Reinkomponenten liegen.
    Notes: Saturated aliphatic polyesters with 1.4:3.6-dianhydrosorbitol units were mixed with poly(vinylchloride) (PVC). The mechanical properties of these mixtures were examined by differential scanning calorimetry, stress-strain experiments, and torsion pendulum measurements. Polyesters containing more than four methylene groups in the acid component are compatible with PVC. These polyesters can serve as plasticizers for PVC. On the contrary, mixtures of PVC with poly(1.4:3.6-dianhydrosorbitol adipate) are incompatible; in this case, at any blend composition, the two glass transition temperatures of the pure components are observed.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 210 (1993), S. 173-196 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Durch radikalische Kettenübertragung ausgelöste Pfropfcopolymerisationen von Polyestern rnit Styrol wurden untersucht. Als Rückgratkette diente ein Modellpolyester aus trans- 1,4-Cyclohexandiol und Sebacinsäuredichlorid. Ferner wurden flüssigkristalline Polyester rnit 1,4 : 3,6-Dianhydrosorbit und 1,4-Anhydroerythrit als Diolkomponenten hergestellt und zur Pfropfcopolymerisation mit Styrol eingesetzt. Polymerblends aus Tetramethylbisphenol A-Polycarbonat und den ungepfropften sowie mit Styrol gepfropften flüssigkristallinen Polyestern wurden durch gemeinsame Fällung von Polymerlösungen erhalten; ihr Verhalten wurde mit Torsionspendelmessungen, dynamisch-mechanischer Thermoanalyse und Elektronenmikroskopie untersucht. Der gepfropfte Polyester erwies sich dabei als wirksamer Phasenvermittler.
    Notes: Graft copolymerizations of polyesters with styrene by free-radical chain transfer reactions were investigated. A model polyester of trans-l,4-cyclohexanediol and sebacoy1 dichloride was used as backbone chain. The graft products were characterized. Furthermore, liquid crystalline polyesters with 1,4 : 3,6-dianhydrosorbitol and 1,4-anhydroerythritol as diol components were synthesized and used in graft copolymerizations with styrene. Polymer blends of tetramethylbisphenol A polycarbonate and the LC-polyester with and without polystyrene grafts were prepared by common precipitation of polymer solutions and their behaviour was examined by torsion pendulum, dynamic-mechanical thermoanalysis and scanning electron microscopy. The grafted polyester turned out to be an efficient phase compatibilizer.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 221 (1994), S. 187-205 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Polyether auf Triazinbasis können mittels phasentransferkatalysierter Polykondensation bei Raumtemperatur und Reaktionszeiten von 1 bis 3 h hergestellt werden. Von mehr als 20 Polyethern wurden Löslichkeiten, Glasübergangstemperaturen, thermogravimetrische Daten, Reißdehnungen, Reißfestigkeiten, Elastizitätsmoduli und Schlagzähigkeiten bestimmt. Von den Polymeren aus 2,4-Dichlor-6-diethylamino-s-triazin und Bisphenol A wurde zusätzlich der Kristallisationsgrad mittels Röntgenweitwinkelstreuung ermittelt. Das Inkrement des 1,3,5-Triazintriylrings wurde bestimmt, so daß die Glastemperaturen einiger Polyether nach van Krevelen berechnet werden konnten.
    Notes: Triazine-based polyethers can be synthesized by phase transfer catalysed interfacial polycondensation at room temperature and reaction times of about 1 to 3 h. In this way, more than 20 polyethers were synthesized and solubilities, glass transition temperatures, thermogravimetric data, elongations at break, tensil strengths, elasticity moduli and impact strengths were determined. In addition, the degree of crystallinity was investigated for the polymer obtained from of 2,4-dichloro-6-diethylamino-s-triazine and bisphenol A by wide angle X-ray diffraction. The increment of the 1,3,5-triazinetriyl ring was determined, which made it possible to calculate the glass transition temperatures of some polyethers according to van Krevelen.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The phase behaviour of methacrylic side chain liquid-crystalline (LC) copolymers, with a spacer-decoupled mesogen in one comonomer and a methyl (MMA) or stearyla (SMA) substituent in the other comonomer, was studied. The mesogen is of the phenyl benzoate type and has a methoxy end group. The LC homopolymer (PLC) has a smectic and a nematic phase. The comonomers MMA and SMA destabilize the LC phase. This effect is compared to the destabilisation caused by end groups in oligomers of PLC. The SMA side chains crystallize so that the SMA copolymers assume a smectic-crystalline bilayer structure. Finally, it is shown that the order of the copolymers affects their mutual miscibility.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Poly(vinylchloride) (PVC) was mixed with various poly(methacrylate)s, poly(carbonate)s and polymers containing nitrile groups (poly(acrylonitrile), poly(styrene-co-acrylonitrile), nitrile rubber, hydrogenated nitrile rubber) and/or C — C double bonds (nitrile rubber, high-impact poly(styrene)). The thermal stability was measured at 180°C in nitrogen, and the evolved HCl was detected by conductometry.It is shown that the nature of the ester group and the content of nitrile groups and C - C double bonds are the dominating factors for the thermal stability of poly(vinylchloride) in these blends. An influence of the miscibility of PVC with the various blend components on the thermal stability can not be clearly detected.Differential scanning calorimetry (DSC) was used as a powerful method to study the stabilizer distribution of heterogeneous PVC/poly(styrene-co-acrylonitrile) and PVC/poly(methylacrylate) blends. It is shown that the stabilizer can be solubilized either in the PVC phase (PVC/poly(methylacrylate)) or in both phases of the blends PVC/poly(styrene-co-acrylonitrile)).
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 220 (1994), S. 199-207 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Cellulose benzoates with degrees of substitution between 2.8 and 2.9 were synthesized in a one-step reaction of cellulose with benzoyl chloride in presence of pyridine as base. Their molecular weights were in the range 140000-100000; the glass transition temperature and the melting temperature were 155 and 274°C, respectively. The esters are readily soluble in organic solvents such as N,N-dimethyl formamide, chloroform and dichloromethane and show good thermal resistance up to 250°C. Because of the brittle character of cellulose benzoate, plasticizer (diethyl phthalate) must be added for the fabrication of films and workable, moulded parts. As shown by stress-strain and impact measurements, the hard and brittle character is retained for plasticizer contents up to 20 wt.-%.
    Notes: Cellulosebenzoate mit Substitutionsgraden von 2,8-2,9 wurden in einer einstufigen Reaktion durch Umsetzung von Cellulose mit Benzoylchlorid in Gegenwart von Pyridin als Base hergestellt. Die Molekulargewichte der Cellulosebenzoate lagen zwischen 140000 und 100000; die mittels DSC gemessene Glastemperatur Tg betrug 155°C, die Schmelztemperatur TS 274°C. Die Ester sind gut löslich in organischen Lösungsmitteln wie N,N-Dimethylformamid, Chloroform und Dichlormethan und besitzen ferner eine gute thermische Beständigkeit bis ca. 250°C. Filme und nacharbeitbare Preßlinge aus Cellulosebenzoat lassen sich aufgrund der hohen Sprödigkeit nur durch Zumischen eines Weichmachers (Diethylphthalat) herstellen. Dabei bleibt das hart-spröde Verhalten, wie Zug-Dehnungs-Versuche und Schlagzähigkeitsmessungen zeigten, bis zu einem Weichmacheranteil von 20 Gew.-% bestehen.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 219 (1994), S. 27-42 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Poly[(2,4-dichlor-6-ethoxy-s-triazin)-alt-(bisphenol A)] (T-BPA) ist ein Polymeres mit interessanten thermischen und mechanischen Eigenschaften; die Monomeren 2,4-Dichlor-6-ethoxy-s-triazin und Bisphenol A sind in technischem Maßstab zu günstigen Preisen verfügbar. Die Reaktionsbedingungen für die Synthese von T-BPA durch phasentransferkatalysierte Polykondensation wurden untersucht und optimiert. Dazu wurde der Einfluß der verschiedenen Reaktionsvariablen wie Temperatur, Reaktionszeit, Art und Konzentration des Phasentransferkatalysators, Monomerkonzentration, Lösungsmittel, Art der Base, Salzzusatz und Konzentration eines Molekulargewichtsreglers auf die reduzierte spezifische Viskosität und die Ausbeute an T-BPA untersucht. Auf diese Weise ist es möglich, T-BPA unter Reaktionsbedingungen herzustellen, die günstig hinsichtlich der Energie- und Anlagekosten sind.
    Notes: Poly[(2,4-dichloro-6-ethoxy-s-triazine)-alt-(bisphenol A)] (T-BPA), a polymer with interesting mechanical and thermal properties, was synthesized by phase transfer catalysed interfacial polycondensation. The reaction conditions for the synthesis of T-BPA were investigated and optimized. The influence of several reaction parameters, such as temperature, reaction time, type and concentration of phase transfer catalyst, concentration of monomers, type of solvent, type of base, salt addition, and molecular weight terminator concentration on the reduced specific viscosity and yield of T-BPA was investigated. As a result, it is possible to synthesize T-BPA at reaction conditions being favourable with regard to the costs of energy and equipment.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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