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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 28 (1991), S. 95-101 
    ISSN: 1573-0867
    Keywords: Phosphate rock dissolution ; soil pH ; solution phosphorus ; phosphorus fractionation ; monocalcium phosphate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Soil Samples were collected from a field experiment conducted to evaluate the agronomic effectiveness of a reactive phosphate rock (PR), Sechura sand, relative to that of monocalcium phosphate (MCP) at different soil pHs and rates of application. The samples were analysed for P soluble in the soil solution and bicarbonate extractable P. The rate of dissolution of PR was calculated from the data on the fractionation of inorganic P. In MCP plots P in the soil solution decreased sharply with time especially at low pHs and high rates of fertiliser application. In PR plots the concentration remained with time at the same as or a slightly higher level than that was found one month after application. Solution concentration of P was lower at very high rates of PR application than at intermediate rates. In both MCP and PR plots bicarbonate extractable P decreased with increasing pH. Bicarbonate extractable P was linearly related to MCP but not to PR applied. The rate of dissolution and the proportion of PR dissolved decreased with increasing rates of PR application but the amount dissolved increased. Phosphate dissolved at high level of PR application did not seem to enhance proportionately either the concentration of P in soil solution or bicarbonate extractable P.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 35 (1993), S. 47-59 
    ISSN: 1573-0867
    Keywords: Partially acidulated phosphate rocks ; phosphate rock reactivity ; soil pH ; compaction ; cogranulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Partially acidulated phosphate rocks (PAPRs) are manufactured by acidulation of PRs with less than the stoichiometric amounts of, usually, phosphoric or sulphuric acids. Products of similar composition to PAPRs are also prepared by cogranulating superphosphate with PRs. For most crops the agronomic value of PAPRs is determined by the availability to plants of their water-soluble P as well as their PR P component. The acid unreacted PR present in the directly acidulated PAPR, is considered to be less reactive than the original PR. This is probably the result of surface coatings of chemical compounds formed during acidulation. Under some soil conditions, in the presence of plants, the PR component probably dissolves faster than the original PR. For seasonal crops, except for fast growing ones such as squash (Cucurbita maxima), reactive PRs partially acidulated so that the final products contain about 50% of its total P in water-soluble form, are generally as effective as fully acidulated superphosphate. For permanent pastures the water P content may be reduced to about 40% of total P without reducing their agronomic effectiveness of the product. In medium P retentive soils pH seems to have little or no influence on the agronomic effectiveness of PAPRs. In highly P retentive soils increasing soil pH reduces the agronomic effectiveness of phosphoric PAPRs apparently by reducing the solubility of the PR component of PAPRs. Even at low pH the dissolution of unreacted PR in sulphuric PAPRs is less than that in phosphoric PAPRs, probably due to the possible coating of calcium sulphate on the residual PR in sulphuric PAPRs. Results on the agronomic effectiveness of PAPRs prepared from unreactive rocks were highly variable and no generalisation could be made regarding the degree of acidulation needed for the products to be consistently effective. Single superphosphate (SSP) cogranulated with reactive rocks (SSP/PR) was agronomically less effective than SSP, and also than phosphoric PAPRs of similar water-soluble P.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1573-0867
    Keywords: Phosphate rock ; soil pH ; andepts ; white clover ; ryegrass ; soil phosphorus ; monocalcium phosphate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The agronomic effectiveness of an unground reactive phosphate rock from Sechura, Peru, was compared with that of monocalcium phosphate in a severely P deficient and highly P retentive soil (vitrandept) over a period of three years. Soil pHs were adjusted to pH 5.1, 5.3, 5.6 and 6.4. The sward consisted mostly of ryegrass (Lolium perenne) and white clover (Trifolium repens). Fertilisers were applied at six rates at pH 5.3 and three rates at other pHs in the first year. For two of the rates fertilisers were reapplied in the second year. Dry matter yields, P uptake and ground cover of clover were determined during the experimental period. In phosphate rock treated plots a negative linear relationship was obtained between soil pH and the logarithm of yield. The agronomic effectiveness of phosphate rock relative to monocalcium phosphate increased with time at all pHs. Calculated at fertiliser rates which produced near maximum yields, relative agronomic effectiveness at soil pHs 5.1, 5.3, 5.6 and 6.4 were respectively 58, 60, 18, and 5 in year one; 118, 125, 77 and 38 in year three. At pH 5.3, as the rate of application increased the relative agronomic effectiveness of the phosphate rock generally decreased in year one but was enhanced in the intermediate rates in years two and three. The data for ground cover of clover gave a similar trend to that for herbage yield and P uptake.
    Type of Medium: Electronic Resource
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