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  • 1990-1994  (4)
Material
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 76 (1994), S. 163-171 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The structural transformations occurring during high-energy mechanical milling and subsequent annealing of YBa2Cu3O7−δ samples have been studied. A high initial oxygen content favors the formation of a metastable (Y0.33Ba0.66)CuO3−x disordered cubic phase. The cubic phase decomposes into a nanocrystalline mixture of Y2BaCuO5 and an yttrium deficient amorphous phase upon further milling. The crystallization enthalpy of the amorphous phase was estimated to be approximately 72.2 kJ/mol with a corresponding activation energy of 800±80 kJ/mol. Upon heating the nanocrystalline cubic phase transforms to the high-oxygen tetra X (O6.77) nonsuperconducting phase. Under oxygen, this last phase is stable up to 930 °C where it transforms to the tetra II low-oxygen (O〈6.4) structure which reverts to the ortho I superconducting phase after adequate cooling. A structural model is proposed in which the formation of coherent domain boundaries and the unusually short c axis associated with the tetra X phase are related to the reordering of the Y-Ba sublattice of the metastable cubic phase. The relative stability of the cubic and tetra X phases as a function of the initial oxygen content before milling indicates that the oxygen concentration may be higher at the domain boundaries.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 79-80 (Jan. 1993), p. 33-46 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 26 (1991), S. 559-568 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The dimensional changes of dendritic and non-dendritic (stir-cast) Zn-Al alloy (ZA-27) were investigated during ageing at temperatures in the range 20–245 °C. The linear expansion of both dendritic and non-dendritic samples increased rapidly with ageing time after about 24 h at 95 °C. An initial normalization treatment led to a large initial growth of the alloy which increased further after prolonged ageing times (≥ 104h). Accelerated ageing tests in the range 75–250 °C showed that increasing the ageing temperature decreased the long term linear expansion of the alloy. In comparing the behaviour of the two materials, the stir-cast material grew less than the dendritic alloy. Extensive SEM and TEM done on as-stir-cast and aged samples showed that the main changes during ageing occurred in the α (FCC) lamellae of the β→α+(Zn) eutectoid, the α phase at the primary αparticles/βeutectoid interface and in the interparticle areas. In the α lamellae and at the interface, zinc precipitated whilst the τ′ phase precipitated in the interparticle areas. It is considered that the occurrence of this latter phase, rich in copper, is responsible for the growth of stir-cast material during ageing.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 13 (1994), S. 963-965 
    ISSN: 1573-4811
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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