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  • 1
    Electronic Resource
    Electronic Resource
    Metal oxidation: An electrochemical perspective (1988)
    Springer
    Oxidation of metals 30 (1988), S. 405-418 
    Details
    ISSN: 1573-4889
    Keywords: metal oxidation ; Wagner theory ; Mott-Cabrera theory
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A general electrochemical theory for the oxidation of metals is presented. The oxidizing metal is viewed as a self-driving electrochemical cell in which the oxide acts as both ionic and electronic conductor. The irreversibility of each of the charge-transfer steps in the reaction mechanism is expressed in terms of an overpotential, the sum of these being equal to the Gibbs free-energy change accompanying the reaction. From this equality, it is possible to calculate the reaction rate as a function of the change in free energy and of such system parameters as oxide conductivity. It is shown that the Wagner theory and the Mott-Cabrera theory can be derived as special cases of the general electrochemical theory. The common basis for the Wagner theory and the Hoar-Price theory of parabolic oxidation is also demonstrated.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00659008
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Sabulodes caberata guenée (Lepidoptera: Geometridae) (1986)
    Springer
    Journal of chemical ecology 12 (1986), S. 2107-2116 
    Details
    ISSN: 1573-1561
    Keywords: Sabulodes caberata Guenée ; Sabulodes aegrotata Guenée ; omnivorous looper ; Lepidoptera ; Geometridae ; sex pheromone ; (Z,Z)-6,9-nonadecadiene ; (Z)-9-nonadecenekw] ; n-nonadecane
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract A 6,9-nonadecadiene, (Z)-9-nonadecene, andn-nonadecane were identified in extracts of sex pheromone glands of femaleSabulodes caberata Guenée. Potential pheromonal activity of gland components was assessed by electroantennogram measurements of gas-chromatographic fractions of abdominal tip extracts. Chemical identification was based on gas chromatography and mass spectrometry of parent compounds, hydrogenation products, ozonolysis products, dimethyl disulfide adducts, and synthesis. The monoene was synthesized via coupling of alkyl and acetylenic intermediates. (Z,Z)-6,9-Nonadecadiene (Z6,Z9-19∶H) was synthesized from methyl linoleate via chain lengthening. SyntheticZ6,Z9-19∶H had the same retention times on polar and nonpolar capillary gas-chromatographic columns as the 6,9-nonadecadiene from the sex pheromone glands. In field testsZ6,Z9-19:H alone produced trap catch of maleS. caberata and addition of (Z)-9-nonadecene orn-nonadecane had no effect on trap catch.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01020313
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Western avocado leafroller,Amorbia cuneana (Walsingham), (Lepidoptera: Tortricidae) (1986)
    Springer
    Journal of chemical ecology 12 (1986), S. 1239-1245 
    Details
    ISSN: 1573-1561
    Keywords: Amorbia cuneana ; Amorbia essigana ; sex pheromone ; sex pheromone component ratios ; Lepidoptera ; Tortricidae ; (E,E)-10,12-tetra-decadien-1-ol acetate ; (E,Z)-10,12-tetradecadien-1-ol acetate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract The most effective lure for maleAmorbia cuneana (Walsingham) in Orange, Ventura, and Riverside counties of California was previously found to be a 1∶1 ratio of (E,E)-10,12- and (E,Z)-10,12-tetradecadien-1-ol acetates. In subsequent field tests in San Diego and Santa Barbara counties, this lure was ineffective. Analysis of sex pheromone glands (SPG) of femaleA. cuneana from these two counties showed theEE:EZ ratio to be about 1∶9 and synthetic lures of this composition were highly attractive in these areas. Analysis of the SPG of a number of females from both areas showed that there were three population types: two in the low ratio areas possessed 37 and 58%EZ, and the third in the high ratio areas possessed 89%EZ.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01012344
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    Paper (German National Licenses)
    Fulltext
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