ISSN:
1572-8927
Keywords:
Conductivities
;
Ion association
;
1∶1 electrolytes
;
acetone
;
dimethylsulfite
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The electrolytic conductances of LiClO4, LiAsF6, NaClO4 and the n-butylammonium salts Bu4NCl, Bu4NClO4, and Bu4NBPh4 (tetraphenylborate) have been determined in dimethylsufite at 25°C. Ion association constants calculated from these data are interpreted in terms of solvent-separated ion pairs (for LiClO4, LiAsF6, and NaClO4), and contact ion pairs (for the n-butyl-ammonium salts). Comparisons are made for analogous electrolytes in acetone, and in which all salts form contact ion pairs.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00644598
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