ISSN:
1612-1112
Keywords:
Thin layer chromatography
;
Column liquid chromatography
;
21H, 23H-Porphine
;
Metalloporphyrin complexes
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary The chromatographic mobility of 21H, 23H-porphine and its Ni(II), Cu(II), Zn(II) and Pd(II) complexes were investigated by high-performance thin-layer chromatography on an octadecyl-bonded, silica gel plate with various polar organic solvents including alcohols, acetonitrile, dimethylsulfoxide and propylenecarbonate. The mobility generally decreases according to the central metal ion of the complex as follows: Zn(II)〉(free porphine)〉Ni(II)〉Pd(II)〉Cu(II). Methanol is a good choice of solvent for the separation of these metal porphine complexes. Successful separation of porphine and the four metal complexes is accomplished within 13 min on a LiChrosorb RP-18 column with methanol eluent.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02257319
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