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  • 1985-1989  (5)
  • Ammonia loss  (2)
  • Analytical Chemistry and Spectroscopy  (1)
  • Nitrogen oxides  (1)
  • Polymer and Materials Science  (1)
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Years
Year
Keywords
  • 1
    ISSN: 1573-0867
    Keywords: Ammonia loss ; denitrification ; nitrogen balance ; algal growth ; transfer processes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Losses of nitrogen were investigated after applications of ammonium bicarbonate and urea to flooded rice at transplanting. Ammonia (NH3) volatilization was determined by direct micrometeorological methods, and total loss of fertilizer nitrogen (N) was measured by15N balance. All the loss appeared to be in gaseous forms, since there was no evidence of leaching and runoff was prevented. The difference between N loss and NH3 loss was thus assumed to be denitrification loss. Both NH3 volatilization and denitrification losses were large, being 39% and 33%, respectively, of the ammonium bicarbonate N, and 30% and 33%, respectively, of the urea N applied by farmers' methods. Ammonia fluxes from the field fertilized with ammonium bicarbonate were very high for two days, and then declined rapidly as the NH3 source in the floodwater diminished. Moderate fluxes from the field fertilized with urea continued over 6 days, but calculations showed that NH3 transfer from floodwater to atmosphere was retarded during the middle period of the experiment, particularly on day 2 when a thick algal scum appeared on the water surface. The results indicate that this algal mass obstructed the transport of NH3 across the water-air interface until the scum was dispersed by wind action. Nevertheless, the prolonged NH3 losses on the urea treatment were due primarily to high floodwater pH values promoted by the strong algal growth during the daylight hours. Nitrogen-15 balance studies showed that incorporation of fertilizer into drained soil substantially increased recoveries of fertilizer N in rice plants and soil compared with incorporation of fertilizer in the presence of standing floodwater. Ammonia loss measurements on these treatments when urea was applied suggested that the improvement in fertilizer N efficiency was due mainly to reductions in NH3 loss.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of atmospheric chemistry 6 (1988), S. 133-147 
    ISSN: 1573-0662
    Keywords: Ammonia loss ; energy balance ; micrometeorology ; water-air transfer
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Vertical flux densities of ammonia, water vapour and sensible heat were measured over a flooded rice field in China following the application of ammonium bicarbonate fertilizer. Aqueous and gaseous phase transfer resistances for ammonia were deduced from these measurements. The aqueous phase resistance was maximal in the morning and least in the afternoon. Stable stratification of the floodwater immediately adjacent to the air-water interface was observed during the morning when evaporation rates were low, and may be responsible for inhibiting the transfer of ammonia to the atmosphere.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1573-0662
    Keywords: Nitrogen oxides ; nitric oxide ; biological production ; surface fluxes ; emission ; uptake ; rice paddy ; nitrogen fertilizer ; urea ; ammonia ; nitrification ; denitrification
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Emissions of nitric oxide and other odd nitrogen oxides (NO x ) from a flooded rice field were studied after urea had been broadcast into the floodwater. The NO x flux from the fertilized area was very low (0.2×10-9 g N m-2 s-1) for the first few days after application of urea and was high (0.95×10-9 g N m-2 s-1) in the subsequent period when significant nitrite and nitrate were present in the floodwater. At night, little if any NO x was exhaled but ambient NO2 was absorbed by the floodwater. An uptake velocity for NO2 of 3×10-4 m s-1 was measured during one night. Maximum NO x losses were observed near 1300 h when temperature and solar ultraviolet light were maximum. While the amounts of nitrogen oxides emitted are of little agronomic importance (∼2×10-3 per cent of the fertilizer nitrogen was lost as NO x during the 10-day study period), they may well be of significance as a source for some gas reactions in the atmosphere and for the global nitrogen cycle. Of the fertilizer nitrogen applied (as urea) approximately 30% was lost to the atmosphere by NH3 volatilization, 15% by denitrification, presumably as N2, and the remainder, less minor losses of NO and N2O, remained in the plant/soil/water system.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 11 (1988), S. 395-400 
    ISSN: 0935-6304
    Keywords: Gas chromatography (GC) ; Fused silica ; Column technology ; Surface modification ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A method has been developed for fabricating fused silica capillary columns which have specific surface properties but still retain the excellent strength, flexibility, and resilience of pure fused silica. By using the Modified Chemical Vapor Deposition process (MCVD), typically used for the production of optical fiber lightguides, inorganic dopants such as Al, Nd, Ge, and P can be introduced into the preform-tube by MCVD. Doped columns have a wide range of specific surface properties, and columns with undoped fused silica prepared by MCVD are more chemically inert and less acidic than columns prepared by conventional methods. This paper describes the method for fabricating capillaries and the initial studies to characterize them.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A system combining ion beam and surface-specific techniques for the analysis of probes exposed in the edge region of the plasma produced by the Joint European Torus (JET) is described. Among examples of the use of the system are the demonstration that 10-40% of the ionic charge flux in the boundary can be due to impurities, erosion and redeposition phenomena can be observed with small probes placed in the plasma boundary, and most of the oxygen observed on collector probes is an artefact resulting from exposure to air.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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