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Mechanistic model of disproportionation of nitrogen monoxide on CaHY-type zeolite (1985)

Kanno, Y. ; Matsui, Y. ; Imai, H.

Springer

Journal of inclusion phenomena and macrocyclic chemistry 3 (1985), S. 461-469

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ISSN: 1573-1111

Keywords: Nitrogen monoxide ; IR spectroscopy ; disproportionation reaction ; CaHY-type zeolite

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Infrared spectra produced by adsorbing, by evacuating and by readsorbing NO on CaHY-type zeolite were examined. The absorption peaks were identified by comparing the spectra produced by adsorbing and by evacuating N2O and NO2. Based upon the experimental evidence, an eight-step mechanism was proposed for the behavior of NO on CaHY-type zeolite. A mechanistic model of the disproportionation reaction of NO was deduced from the variation of the spectra with time.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00657498

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