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  • 1985-1989  (5)
  • Inorganic Chemistry  (4)
  • Electron microscopy
  • sol-gel
  • 1
    Electronic Resource
    Electronic Resource
    Immunologische und elektronenmikroskopische Befunde eines ungewöhnlichen Falles von M. Whipple (1985)
    Springer
    Journal of molecular medicine 63 (1985), S. 176-183 
    Details
    ISSN: 1432-1440
    Keywords: Whipple's disease ; Electron microscopy ; Disturbed cellular immunology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Whipple's disease is a curious disorder with the involvement of many organ systems, primarily gut, synovium and the central nervous system, characterized by the presence of numerous proliferating bacteria in tissue macrophages and other cell types. While clinically this disease entity has previously been defined by the classical triad of diarrhoea, malabsorption and weight loss, some patients do not show these features. In this report, a clinically unusual case of Whipple's disease is described presenting with high persistent fever, severe arthralgias and headaches, but without malabsorption, diarrhoea or weight loss. Nevertheless, the histological and electron microscopical pictures demonstrated the typical findings of intracellular micro-organisms along with the presence of bacteria in Schwann nerve cells, which has only once been described previously. Immunological findings before treatment demonstrated a decrease of T cells with the helper/inducer phenotype, and a concomitant rise in cells with the suppressor/cytotoxic phenotype, an elevation of “activated” Ia positive T cells and a significant reduction of T cell mitogenic responsiveness. Of special interest, after a successful treatment these immunological abnormalities shifted to normal with the exception of a still elevated number of Ia+ T cells. The discussion of this unusual case of Whipple's disease includes — besides possible cellular immunological abnormalities — genetic factors, especially since this patient was HLA-B-27-positive as was his son who is suffering from ankylosing spondylitis.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01732172
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  • 2
    Electronic Resource
    Electronic Resource
    New Prophosphatranes: Novel intermediates to five-coordinate phosphatranesDedicated to Professor Kurt Issleib on his 70th Birthday (1989)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 578 (1989), S. 75-80 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Neue Prophosphatrane: Neuartige Zwischenstufen auf dem Wege zu pentakoordinierten PhosphatranenDie Reaktion von N(CH2CH2NHMe)3 mit P(NMe2)3 oder P(NMe2)2Cl ergibt die Phosphatranvorstufe N(CH2CH2NMe)3P. Dessen Umsetzung mit Oxydationsmitteln ode Elektrophilen führt zu nicht-transannular-stabilisierten, tetrakoordinierten Derivaten N(CH2CH2NMe)3P—X, (X: O, S, Se, N3Ph, NPh, CS2, 1/2 PtCl2). Die Strukturen der beschriebenen Verbindungen werden anhand ihrer 1H-, 13C- und 31P-NMR-Daten diskutiert.
    Notes: The reaction of N(CH2CH2NHMe)3 with P(NMe2)3 or P(NMe2)2Cl yields the phosphatrane precursor N(CH2CH2NMe)2P,4. With oxydizing agents or electrophiles 4 is converted to the untransannulated four-coordinated derivatives N(CH2CH2NMe)3P—X, (X: O, S, Se, N3Ph, NPh, I CS2, 1/2 PtCl2). The structures of the compounds described are discussed by 1H, 13C, and 31P n.m.r. data.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19895780109
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  • 3
    Electronic Resource
    Electronic Resource
    C-metallierte Aminophosphine 1. α-lithiierte DimethylaminophosphineProfessor Marianne Baudler zum 65. Geburtstage am 27. April 1986 gewidmet (1986)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 535 (1986), S. 47-55 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: C-metalated Aminophosphines. 1. α-lithiated DimethylaminophosphinesThe preparation of dimethylaminophosphines of the general formula Z—CH2—Pdma2 and (Z—CH2)2Pdma, respectively (Z = (CH3)3Si, C6H5), their monometalation and the reactions of these metalated species with chlorosilanes, bis-(dimethylamino)-chlorophosphine and trimethylsilylmethyl-dichlorophosphine are described. The n.m.r. spectra of the prepared compounds are discussed.
    Notes: Es wird die Darstellung von Dimethylaminophosphinen der allgemeinen Formulierung Z—CH2—Pdma2 bzw. (Z—CH2)2Pdma, deren Monolithiierung zu Z—CH(Li)—Pdma2 bzw. Z—CH(Li)—P(dma)—CH2—Z (Z = (CH3)3Si, C6H5) und die Reaktionen dieser lithiierten Spezies mit Chlorsilanen sowie Bis-(dimethylamino)-chlorphosphin und Trimethylsilylmethyldichlorphosphin beschrieben. Die NMR-Daten der dargestellten Verbindungen werden diskutiert.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19865350407
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  • 4
    Electronic Resource
    Electronic Resource
    Über die Cycloaddition von Dithiocyan und Trithiocyan mit Hexafluoraceton und Folgeprodukte aus der Spaltung der Schwefel-Schwefel-Bindung mit elementarem Chlor im Dithiocyan-Hexafluoraceton-AdduktProfessor Gerhard Gattow zum 60. Geburtstage am 6. Februar 1986 gewidmet (1986)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 532 (1986), S. 131-136 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Cycloaddition of Dithiocyanogen and Trithiocyanogen with Hexafluoroacetone and Products of the Cleavage of the Sulfur-Sulfur Bond in Dithiocyan-Hexafluoroacetone Adduct by Elemental ChlorineThe reaction of dithiocyanogen and trithiocyanogen with hexafluoroacetone (HFA) leads to the cycloaddition products (SCN)2 · 4 HFA 1 and S(SCN)2 · 4 HFA 2. These are the first reactions of (SCN)2 and S(SCN)2 without cleavage of the S - S bonds. Elemental chlorine cleaves in 1 the S—S bond and 3 is formed. In 3 the chlorine atom can be replaced by the rests  - CN 4, (C6H11)2N -  5, and n-C4H9- 6. 6 eliminates one molecule of HFA by warming up and the four-membered ring 7 is formed. The compounds were characterized on the basis of mass and nmr spectra.
    Notes: Die Reaktion von Dithiocyan und Trithiocyan mit Hexafluoraceton (HFA) führt zu den Cycloadditionsprodukten (SCN)2 · 4 HFA 1 und S(SCN)2 · 4 HFA 2. Es sind die ersten Reaktionen des (SCN)2 und S(SCN)2, die nicht unter Spaltung der S—S-Bindungen verlaufen. Durch elementares Chlor wird 1 an der S—S-Bindung gespalten und es entsteht 3. In 3 kann das Chloratom durch die Reste  - CN 4, (C6H11)2N -  5 und n-C4H9- 6 ersetzt werden. Beim Erwärmen verliert 6 ein Molekül HFA und es entsteht der viergliedrige Ring 7. Die Verbindungen wurden anhand ihrer Massen- und NMR-Spektren eindeutig charakterisiert.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19865320118
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  • 5
    Electronic Resource
    Electronic Resource
    Reaktion des aktivierten 1,2-Diphosphinobenzens mit Diphenylcarbodiimid (1985)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 529 (1985), S. 216-221 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Reaction of Activated 1,2-Diphosphinobenzene with Diphenylcarbodiimide.The reaction behaviour of 1,2-(Ptms2)2C6H4 and 1,2-(PHLi)2C6H4 towards Ph—N=C=N—Ph leads to phosphaguanidino derivatives of 1,2-diphosphinobenzene and 2-(phenyltrimethylsilylamino)-3-trimethylsilyl-1,3-benzodiphosphole. The structure of the compounds are discussed on the basis of their n.m.r. spectra.
    Notes: Die Umsetzungen von Tetrakis(trimethylsilyl)-1,2-diphosphinobenzen sowie von 1,2-Di(lithiophosphino)benzen mit Diphenylcarbodiimid führen zu Phosphaguanidino-derivaten des 1,2-Diphosphinobenzens sowie zum 2-(Phenyl-trimethylsilylamino)-3-trimethylsilyl-1,3-Benzodiphosphol. Die Strukturen der dargestellten Verbindungen werden anhand der NMR-Daten diskutiert.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19855291027
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