ISSN:
0887-624X
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Four novel symmetric tri-n-alkyltin fluorides were prepared. In this homologous series, melting point decreases with increase in the carbon chain length while an x-ray diffraction study shows an increase in amorphousness. 1H-NMR spectra in cyclohexane, a nonpolar solvent in which these compounds form long polymeric chain, show a peak broadening effect due to high solution viscosity at very low solute concentration. Contrary to this, the spectra in CDCl3, a polar solvent in which these compounds are monomeric, show well resolved and narrow peaks. IR frequencies for Sn—C vibrations have been assigned.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pola.1989.080270327
Permalink
