ISSN:
1572-8927
Keywords:
Thorium
;
fluoride
;
complexation
;
enthalpy
;
calorimetry
;
ionic bonding
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Titration calorimetry has been utilized to study the aqueous solution chemistry of the Th4++F− system. Enthalpies of the first three complexation reactions have been measured at an ionic strength of 0.5M at 25°C, and corresponding entropy values have been calculated. Results for the first complex are in good agreement with an established electrostatic model of metal-fluoride bonding.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00652984
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