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Digitale Medien

Measurement of the enthalpies of complexation of thorium with multiple fluoride ligands (1989)

Grant, P. M. ; Kinard, W. F. ; Baisden, P. A.

Springer

Journal of solution chemistry 18 (1989), S. 211-216

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Details

ISSN: 1572-8927

Schlagwort(e): Thorium ; fluoride ; complexation ; enthalpy ; calorimetry ; ionic bonding

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract Titration calorimetry has been utilized to study the aqueous solution chemistry of the Th4++F− system. Enthalpies of the first three complexation reactions have been measured at an ionic strength of 0.5M at 25°C, and corresponding entropy values have been calculated. Results for the first complex are in good agreement with an established electrostatic model of metal-fluoride bonding.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF00652984

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