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  • 1985-1989  (2)
Material
Years
  • 1985-1989  (2)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 17 (1987), S. 1198-1202 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Thick, freestanding, flexible films of polypyrrole have been prepared from propylene carbonate solutions of pyrrole monomer containing tetra-ethyl ammoniump-toluene sulphonate electrolyte The conductivity of the films was found to vary with orientation of the sample, deposition temperature and time. Conductivities of up to 338.4 S cm−1 were attained with samples prepared at 0°C. XRD analyses have revealed a difference in structure with sample orientation which affects the conductivity of the material significantly.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 23 (1988), S. 2102-2106 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Polypyrrole films, typically 0.2 mm thick, were prepared by electrodeposition withp toluene sulphonate as dopant anions. Conductivities of up to 340 S cm−1 were found, comparing favourably with other cited examples. Conductivity along each sample was found to be much greater than across: such asymmetry may be exploitable. Electrodeposition temperatures (0° C) lead to higher conductivities than at 25° C. The structure was amorphous as indicated by X-ray diffraction, and the morphology was found to be nodular by using optical and scanning electron microscopy. Films were found to be quite strong and tough, although some reduction in mechanical performance was found after ageing in air. Fracture surfaces of tensile test pieces suggest a layered structure, with little evidence for viscous deformation being evident.
    Type of Medium: Electronic Resource
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