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  • 1985-1989  (13)
  • 1
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 52 (1988), S. 1056-1058 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: New types of oxide layers of Si and GaAs were grown on (100) Si and (100) GaAs substrate by using an electron beam doping technique at 40–50 °C. The surfaces of the semiconductors were irradiated with a fluence of ∼5×1017 electrons cm−2 at 7 MeV. The samples were put in an isothermal circulating water bath with a thermoregulator. The electronic structure of the oxide layers was observed by an x-ray photoelectron spectroscopy (XPS). The chemical shifts between oxidized and nonoxidized Ga signals for Auger electron spectra and 3d XPS spectra were nearly equal to that in the conventional plasma-grown oxidation. It was suggested that the electron beam doping, oxidation, and epitaxy were caused by plasma reaction.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 54 (1989), S. 2559-2561 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Effects of rapid thermal processing (RTP) on 200-nm-thick SiO2/GaAs interfaces have been studied with x-ray photoelectron spectroscopy. RTP has been performed at 910 °C for 9 s with the heating rate of 53 °C/s. Rapid diffusion of Ga through SiO2 occurs. The diffusion coefficient of Ga in SiO2 for RTP is found to be about two orders of magnitude larger than that for conventional furnace processing. The heating rate dependence of the Ga outdiffusion is also reported in the range 31–83 °C/s. In addition, slight loss of As is observed. These results are discussed on the basis of the RTP-induced thermal stress between SiO2 and GaAs.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 53 (1988), S. 1596-1598 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A long-range order of Al0.5Ga0.5P layers grown by electron beam epitaxy on a (100) GaP substrate has been detected. Surfaces of Al layers deposited by vacuum evaporation on GaP wafers were irradiated with a fluence of (1–5)×1017 electrons cm−2 at 7 MeV and 50 °C. It is speculated that since a great number of electron-hole pairs are created, the strong enhancement of the diffusion of Al atoms may be caused by the energy release mechanism and an Al interstitial may preferably occupy a Ga site by the "kick-out'' mechanism and for the formation of much stabler bonds between group III and V atoms.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 51 (1987), S. 2130-2132 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Solid phase epitaxial layers of Al0.25Ga0.75P, Al0.5Ga0.5P, and Al0.75Ga0.25P were grown on (111), (100), and (110) GaP substrates, respectively, by using an electron beam epitaxy technique at 50 °C. The surfaces of Al layers deposited by vacuum evaporation on GaP wafers were irradiated with a fluence of (0.1–1.0)×1018 electrons cm−2 at 7 MeV. After the irradiation and removal of the Al layers, evidence of the creation of epilayers that had been formed before annealing was obtained from a secondary-ion mass spectrometer, an x-ray diffractometer, and a reflection high-energy electron diffractometer.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 54 (1989), S. 831-833 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The distributions of deep levels in semi-insulating GaAs before and after rapid thermal processing (RTP) at 800 °C are obtained by the contactless measurement of the optically injected excess carrier signal height by reflectance microwave prober method. The deep levels in the liquid-encapsulated Czochralski-grown 2 in. GaAs wafer are redistributed by RTP, and its spatial variation shows a W-shaped pattern along the 〈100〉 radial direction. Furthermore, the distribution of deep levels in the RTP wafer corresponds to the crystallographic slip generation pattern, which is relief of the thermal stress during RTP, examined by x-ray topography. The redistribution of the deep levels is due to the production of the principal deep level EL2 by RTP.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 52 (1988), S. 60-62 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Solid phase epitaxial layers of AlxGa1−xSb (x(approximately-equal-to)0.26–0.28) were grown by using an electron beam doping method on a (100)GaSb substrate at 50 °C. Surfaces of Al layers deposited by vacuum evaporation on GaSb wafers were irradiated with a fluence of 0.1–5.6×1018 electrons cm−2 at 7 MeV. After the irradiation and removal of the Al layer, the epilayers with a thickness of ∼400 A(ring) before annealing were measured by a secondary-ion mass spectrometer, an x-ray photoelectron spectroscope, an x-ray diffractometer, and a reflection high-energy electron diffractometer.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 63 (1988), S. 414-420 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Rapid thermal annealing (RTA) using halogen lamps for Si-implanted (250-keV, 2×1013 cm−2 dose) semi-insulating liquid-encapsulated Czochralski GaAs has been investigated by deep level transient spectroscopy. RTA has been performed at 700, 800 and 900 °C for 6 s with SiO2 encapsulation. For comparison, conventional furnace annealing (FA) has also been performed at 800 °C for 20 min. In the RTA samples at 700 °C, three electron traps NI1 (Ec−0.53 eV), NI4 (Ec−0.63 eV), and EL2 (Ec−0.78 eV) are observed on the Cr-doped substrate, while the traps NI1, EL2, and NI3 (Ec−0.47 eV) are observed on the undoped substrate. In RTA samples above 800 °C, the electron trap NI2 (Ec−0.55 eV) or EL2 is dominant and traps NI1, NI3, and NI4 are not detected. It is possible that three traps NI1, NI3, and NI4 are residual defects produced by Si implantation. The low concentration of the trap EL2 in FA samples is due to the out-diffusion of it. This phenomenon can be related with the change of the stoichiometry in the implanted layer by the formation of the transition region at the SiO2 /GaAs interface during FA. The notable spatial variation of the trap NI2 is observed across the wafer. On the other hand, the peculiar spatial distribution of the trap EL2 is not observed across the RTA sample. Furthermore, the trap EL2 concentration does not depend on RTA temperatures. It is possible that the spatial distribution of the trap EL2 across the RTA sample is changed by Si implantation and RTA.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 62 (1987), S. 528-533 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Rapid thermal processing (RTP) using halogen lamps for liquid encapsulated Czochralski grown GaAs doped with Si has been studied by deep-level transient spectroscopy, capacitance-voltage, and photoluminescence measurements. RTP is performed at 700, 800, and 900 °C for 6 s with and without SiO2 encapsulation. Three electron traps ED1(Ec −0.26 eV), ED2(Ec −0.49 eV), and ED3(Ec −0.55 eV) are produced depending on RTP conditions. The trap ED1 is observed in all RTP samples, and its depth profiles vary with RTP conditions. The decrease of the shallow donor concentration occurs for RTP samples above 800 °C, especially for those without encapsulation. It is thought that these results, which are peculiar to the RTP method, are related to the production of As interstitials and As vacancies by the large thermal stress induced by the rapid heating for RTP. The decrease of the concentration of trap EL2(Ec −0.81 eV) is not observed with RTP as reported in the furnace processing. This is due to the effect of the short-time processing of RTP.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 65 (1989), S. 606-611 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Variations of deep levels in Si-doped molecular-beam-epitaxial (MBE) n-GaAs layers by rapid thermal processing (RTP) using halogen lamps were investigated by deep level transient spectroscopy. RTP was performed at 700, 800, and 900 °C with the face-to-face configuration. Native deep levels M1 (Ec−0.18 eV), M3 (Ec−0.33 eV), and M4 (Ec−0.51 eV) in MBE n-GaAs are annealed out by RTP at 900 °C. The metastable electron trap N1 (Ec−0.5∼0.7 eV) and the midgap electron trap EL2 (Ec−0.82 eV) are produced by RTP at 700, 800, and 900 °C. Two electron traps N2 (Ec−0.36 eV) and N3 (Ec−0.49 eV) are produced by RTP at 900 °C. The peculiar spatial distribution of N1 and EL2 are observed across the RTP layers. In particular, the EL2 distribution is found to be a W-shaped pattern. It is supposed that this peculiar shape of the spatial variation is consistent with that of the thermal stress induced by RTP. In addition the spatial variations of EL2 are suppressed by use of the guard ring composed of GaAs pieces, since it prevents the thermal stress during RTP, but EL2 remains at uniform concentration of ∼1014 cm−3 across the RTP layer. It seems that the thermal stress enhances the production of the trap EL2. On the other hand, the trap N1 is found to disappear by the use of the guard ring composed of GaAs pieces. We also discuss the difference of deep levels between MBE and bulk GaAs after RTP.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 62 (1987), S. 1298-1304 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Majority-carrier traps in p+n diodes fabricated by rapid thermal annealing (RTA) of Zn-implanted GaAs0.6P0.4:Te and in Schottky diodes fabricated on GaAs0.6P0.4:Te after only RTA were studied using deep-level transient spectroscopy (DLTS). RTA using halogen lamps was performed in the temperature range 830–1000 °C for approximately 6 s without any encapsulant. Two electron traps E1 and E2 were observed for both p+n and Schottky diodes and were found to have thermal emission activation energies of 0.20 and 0.36 eV, respectively. The broadened DLTS spectrum was observed and reproduced using the Gaussian distribution for thermal emission activation energies of these traps. Furthermore, traps E1 and E2 have thermal activation energies of 0.09 and 0.24 eV for electron capture, respectively. It is considered that these traps are native defects and may belong to donor-related (DX) centers. Depth profiles of shallow donors and traps were determined using capacitance-voltage measurements because of anomalously high concentrations of these traps. Shallow donor and trap concentrations were found to decrease over several μm from the surface for RTA Schottky diodes above ∼900 °C, but were observed to be uniform for RTA p+n diodes. The concentrations calculated for shallow donors and trap E2 by RTA at 1000 °C decreased exponentially with depth. The difference between p+n and Schottky diodes, and the possible mechanism for the decrease of shallow donor and trap concentrations by RTA are discussed. It is possible that the decrease of shallow donor and trap concentrations by RTA is due either to their interaction with vacancies produced near the surface or to their out-diffusion.
    Type of Medium: Electronic Resource
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