ISSN:
0935-6304
Keywords:
Gas chromatography
;
Capillary, glass
;
Carbohydrate enantiomer separation
;
New chiral stationary phases
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
New chiral polymers have been prepared by conversion of cyano groups of polysiloxanes XE-60 and OV-225 into carboxylic groups and subsequent coupling to give the respective S-valine-R-α-phenyl-ethyl amide. In contrast to the corresponding stationary phases with S-α-phenylethyl amide groups, which have been used for the resoultion of trifluoroacetylated hexose derivatives, the new phase show high enantioselectivity for pentose and 6-deoxyhexose derivatives.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jhrc.1240041103
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