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  • 1980-1984  (7)
  • Physics  (4)
  • Sulfur  (2)
  • Acetylcholine esterase  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Rhythmic dentinogenesis in the rabbit incisor: Allometric aspects (1980)
    Springer
    Calcified tissue international 32 (1980), S. 45-53 
    Details
    ISSN: 1432-0827
    Keywords: Dentin ; Periodicity ; Allometry ; Calcium ; Sulfur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine , Physics
    Notes: Summary We have described differences in the aspects of biological rhythms for calcium and sulfur deposition on the labial and lingual sides of the growing rabbit incisor, where growth occurs along a spiral axis. The calcium oscillations appear to be smoother on the labial side than on the lingual side. The lingual side is characterized by high-frequency rhythms with high amplitudes which possess the greatest percent of the power (Fourier analysis). These observations also reflect a difference in behavior of the mean Ca concentration across the labial and lingual sides. Sulfur rhythms on the labial side have higher amplitudes than those on the lingual side, but systematic differences in distribution of power between high and low frequencies is not as pronounced as in the case of Ca. The differences in Ca rhythms reflect differences in the growth rates of incisors on either side of the spiral axis. The labial side grows slightly faster than the lingual side, and its odontoblasts secrete Ca along the spiral axis and toward the pulp cavity at the same time. Thus the resultant direction of growth is more nearly opposite the extension of the occlusal end on the labial side, and Ca is consequently deposited over a wider area relative to that on the lingual surfaces. On the lingual side, Ca is deposited within a more limited area, and growth must therefore be continuous at high frequencies. The distribution of Ca on both sides of the tooth reflects these differences in growth rate and periodicity in two ways. First, given a unit area of tooth, the calcium concentration on the labial side is less than that of the lingual side. Second, whereas the calcium concentration on the labial side declines rapidly from the enamel-dentin junction to the pulp cavity, it is uniformly high across the lingual side because its growth is more continuous at high frequencies.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02408520
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  • 2
    Electronic Resource
    Electronic Resource
    Rhythmic dentinogenesis in the rabbit incisor: Circadian, ultradian, and infradian periods (1980)
    Springer
    Calcified tissue international 32 (1980), S. 29-44 
    Details
    ISSN: 1432-0827
    Keywords: Rabbit ; Dentin ; Calcium ; Sulfur ; Periodicity ; Circadian ; Ultradian
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine , Physics
    Notes: Summary We have identified a variety of biological rhythms involved in the apposition and mineralization of dentin in the rabbit incisor. Animals were injected during the day or night with lead acetate at 2-week intervals—to provide biological time markers in forming dentin—and transverse undecalcified sections of the lower incisors were prepared for electron microprobe analysis. The positions of the lead markers were identified, and the continuous distribution of calcium and sulfur was measured at 1 µm intervals between the markers. In thin sections stained with hematoxylin after decalcification, the widths of a series of structural increments (bands) were measured with an ocular micrometer. Fourier analysis of the data revealed spectra of structural and compositional rhythms with a range of periodicities which extended from a matter of hours [ultradian (〈24 h)] to days [infradian (〉24 h) and circadian (approximately 24 h)]. The structural and compositional rhythms appeared to be independent to the extent that they did not necessarily have the same periods, or amplitudes. Nor were there simple phase relationships between all of the rhythms. At some times, Ca and S fluctuations are inversely proportional (180° out of phase), but in other cases they are directly proportional or out of phase by varying degrees other than 180°. The analyses thus suggest that calcium and sulfur deposition (representing mineral and glycosaminoglycan deposition, respectively) are not simply inversely proportional, and that the hematoxylin-stained structural increments did not solely reflect differences in the distribution of the mineral components in dentin.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02408519
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  • 3
    Electronic Resource
    Electronic Resource
    Morpholine vapour inhalation and interactions of simultaneous nitrite intake (1983)
    Springer
    Archives of toxicology 53 (1983), S. 143-150 
    Details
    ISSN: 1432-0738
    Keywords: Morpholine ; Nitrite ; Axons ; Acetylcholine esterase ; Creatine kinase ; Succinate dehydrogenase
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract Male Wistar rats exposed intermittently to 300 ppm (12.5 μmol/l) morpholine vapour 5 days a week for 6 h daily during 4–15 weeks displayed an increasing brain solvent content analyzed by a sensitive gas chromatographic method. Rats drinking water which contained 150 mg NaNO2/l during the vapour exposure period showed initially larger brain solvent concentrations which began to decrease after 8 weeks. Fat solvent concentrations were a fraction of those detected in brain of the solvent-exposed animals or of those in the combined exposure. Nitrite exposure alone caused decreased spinal cord axon acetylcholine esterase activity after 8 weeks while this effect was noted in the combined exposure only at 8 weeks disappearing later on. Axonal succinate dehydrogenase activity was below the controls in the combined exposure throughout the study, and combination also caused persistent increase in the muscle creatine kinase activity. The morpholine-induced effects were less remarkable. The results point at pharmacokinetic interaction between the solvent and nitrite with its own effects on energy metabolism. No N-nitrosomorpholine was found although other metabolic interactions could not be excluded.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00302722
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  • 4
    Electronic Resource
    Electronic Resource
    Photorearrangements of hydrocarbon polymers with pendant double bondsPresented at the Division of Polymer Chemistry at the ACS/CSJ Chemical Congress, Honolulu, Hawaii, April 1979. (1980)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 18 (1980), S. 2543-2560 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A study was made of the microstructural changes that occur in ultraviolet irradiation under vacuum of thin films of 1,2-poly(cis-1,4-hexadiene) (CHD), 1,2-poly(trans-1,4-hexadiene) (THD), 1,2-poly(trans-1,3-pentadiene) (TPD), equibinary (1,2,-1,4) polybutadiene (EB), and equibinary (3,4-1,4) polyisoprene (EI). These polymers - all containing pendant double bonds - undergo important photoinduced loss of unsaturation, presumably through cyclization of the double bonds, by analogy to the previously reported photocyclization of 1,2-polybutadiene (VB) and 3,4-polyisoprene (VI)films. For the equibinary polymers, which contain internal as well as external (or pendant) double bonds, the loss of unsaturation is considered to involve photocyclization of 1,2-1,4 and 1,2-1,2 dyads in EB and of 3,4-1,4 and 3,4-3,4 dyads in EI. Accompanying thecyclization process in CHD, THD, and TPD is a direct photochemical cis-trans isomerization of —CH=CH—double bonds analogous to that originally noted for 1,4-polybutadiene. The photorearrangements in the above polymers with pendant double bonds were compared to the corresponding thermally induced rearrangements reported previoulsy;for VB and VI, in particular, the thermal, photo-and radiation-induced cycli-zations were found to be very similar, possibly having a common nonradical, nonionic mechanism involving excited double bonds.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1980.170180813
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  • 5
    Electronic Resource
    Electronic Resource
    Photoconductivity of poly(hexamethylene adipamide) (1980)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 18 (1980), S. 523-527 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Photocurrents induced by pulsed ultraviolet light in polyhexamethylene adipamide (nylon-66) have been studied. Two transient photocurrents are observed for light wavelenghts shorter than 3000 Å;. The first one is weakly field and temperature dependent and has been ascribed to electron photoinjection. On the whole, the time dependence of the two photoresponses suggests the possible formation of a space charge in the material.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1980.180180311
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  • 6
    Electronic Resource
    Electronic Resource
    Thermal expansion of epoxy-resin/particle composites - a size effect (1980)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 18 (1980), S. 217-226 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The thermal expansion of epoxy-resin (Epikote 828)/particle composites has been measured in the range 77 to 450 K. The fillers used were Cu spheres (seven sizes from 5 to 150 μm diameter) and glass ballotini spheres (three sizes from 3.5 to 200 μm diameter). The volume concentrations used were 0.3 and 0.5 for Cu and 0.3 for glass. The experiments show that the addition of filler raises the glass transition temperature Tg, especially for fine particles. Below the normal value of Tg the thermal expansion is independent of particle size while above Tg the expansion is considerably smaller for samples containing the smaller particles. The effect is more pronounced for Cu than for glass filler. In addition a rapid heating rate reduces the expansion for specimens containing smaller particles but it does not effect the expansion for those containing large particles. The results, which are discussed in the light of the work of other authors, suggest that the addition of particles increases Tg by changing the nature of the polymer not only immediately at the particle surface but also for a considerable distance into the polymer itself. This probably occurs because the epoxy bonds strongly to the particles and this inhibits segmental rotations of the polymer even at considerable distances from the particle surface.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1980.180180204
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  • 7
    Electronic Resource
    Electronic Resource
    Synthesis of carbonate-containing high temperature poly(arylene-siloxanylenes) (1982)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 20 (1982), S. 1-13 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A method for the first synthesis of high molecular weight carbonate-containing siloxanylene polymers was successfully developed. The procedure covered the preparation and polymerization of pure carbonate-containing bis-silanols which included bis(4-hydroxydimethylsilylphenyl)-carbonate, bis[4-(1-hydroxy-1,1,3,3-tetramethyldisiloxanyl)-phenyl] carbonate, and their meta analogs. Because conventional siloxane polymerization methods, such as the heterocondensation of bis-silanols with diaminosilanes or homocondensation reactions catalyzed by alkali reagents, decomposed carbonate linkages, a new polymerization technique that involved the use of phosgene was used. The procedure was both facile and effective in the polymerization of other arylene bis-silanols.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1982.170200101
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