ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
On the Pyrolysis of Pent-1-ene-4,4,5,5,5-d5The distribution of deuterium in the main products of thermal decomposition of pent-1-ene-4,4,5,5,5-d5 at 550 to 650°C was studied and interpreted. The results include conclusions on kinetic isotope effects, on relative reactivities of different C-H-bonds, on the proportion of terminal and nonterminal addition of methyl radicals, and on the importance of a radical isomerisation reaction. It was shown that the molecular decomposition (Retro-En-Reaction) cannot successfully compete with the radical way in the temperature range above 600°C
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19833250504
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