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A universal representation of the thermodynamic properties of fluids in the critical region (1984)

Sengers, J. V. ; Levelt Sengers, J. M. H.

Springer

International journal of thermophysics 5 (1984), S. 195-208

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Details

ISSN: 1572-9567

Schlagwort(e): critical-point universality ; critical region ; equation of state ; ethylene ; isobutane ; scaling laws ; steam ; thermodynamic properties

Quelle: Springer Online Journal Archives 1860-2000

Thema: Physik

Notizen: Abstract To characterize the behavior of the thermodynamic properties of systems near a critical point, systems are grouped into universality classes. Systems within a universality class have the same universal critical exponents and scaling functions. Specifically, fluids are expected to belong to the universality class of three-dimensional Ising-like systems for which the universal quantities have been calculated with considerable accuracy. A scaled fundamental equation is presented which incorporates these theoretical predictions. Results obtained for various technologically important fluids, namely ordinary steam, heavy steam, ethylene, and isobutane, are discussed.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF00505500

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