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  • 1980-1984  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    Molybdän(VI)-fluorid-pentafluorotellurate(VI) und Molybdän(VI)-oxid-fluorid-pentafluorotellurate(VI): MoFn(OTeF5)6-n und MoOFn(OTeF5)4-n (1981)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 477 (1981), S. 95-100 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Molybdenum(VI)fluoride-pentafluorotellurates(VI) and Molybdenum(VI)oxide-fluoridepentafluorotellurates(VI): MoFn(OTeF5)6-n and MoOFn(OTeF5)4-nIn MoF6 fluorine can be replaced by F5TeO-groups by means of B(OTeF5)3. Rearrangement reactions and internal fluorination finally leads to MoFn(OTeF5)6-n and MoOFn(OTeF5)4-n.
    Notes: Die Substitution von Fluor durch F5TeO-Gruppen in MoF6 mittels B(OTeF5)3 führt, bedingt durch Dismutationsreaktionen und interne Fluorierung, zu MoFn(OTeF5)6-n und MoOFn(OTeF5)4-n.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19814770611
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Wolfram(VI)-fluorid-pentafluorotellurate(VI): WFn(OTeF5)6-n (1981)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 480 (1981), S. 7-12 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Tungsten(VI) Fluoride Pentafluorotellurates(VI): WFn(OTeF5)6-nIn WF6 fluorine can be replaced by F5TeO groups by means of B(OTeF5)3 to form WFn(OTeF5)6-n. Isolation was achieved for WF5OTeF5 and cis-WF4 (OTeF5)2. Compounds with n 〉 2 have been identified by 19F-nmr spectroscopy. The ligand behaviour of the F5TeO group is compared to OMe and OPh.
    Notes: Die Substitution von Fluor durch F5TeO-Gruppen in WF6 mittels B(OTeF5)3 führt zu WFn(OTeF5)6-n. WF5OTeF5 und cis-WF4(OTeF5)2 konnten isoliert werden. Die Verbindungen mit n 〉 2 wurden durch 19F-NMR identifiziert. Das Ligandenverhalten der F5TeO-Gruppe wird mit OMe und OPh verglichen.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19814800902
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
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