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  • 1975-1979  (2)
  • 1965-1969  (2)
  • 1880-1889
  • Biochemistry and Biotechnology  (2)
  • Physics  (2)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 7 (1965), S. 471-490 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The growth of Thiobacillus Thiooxidans, utilizing sulfur in three media, was studied by observing changes in halfcell emf, bacterial cell count, and acid production, all as a function of time. A comparison of the biological halfcell emf with comparable control halfcells reveals that T. thiooxidans makes an electrochemical contribution to halfcell voltage. A change from the more complex medium of Skerman's mineral salts to ATCC allowed a clearer delineation of the ability of T. thiooxidans to make an electrochemical contribution. Reproducible biological halfcell emf's were obtained when the ferrous sulfate was removed from the ATCC medium. One halfcell, consisting of T. thiooxidans utilizing sulfur in ATCC, was observed over a 111-day period. During this time, the initial halfcell voltage of -0.35 V. decreased to a value of -0.64 V. (hydrogen emf series). T. thiooxidans, in utilizing sulfur, produces only sulfate ion, thereby simplifying the identification of an electrochemical contribution during growth.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 19 (1977), S. 1895-1897 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 17 (1979), S. 3797-3810 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Several N-vinylarylamines have been prepared by direct N-vinylation of arylamine salts with acetylene at atmospheric pressure. Nuclear magnetic resonance (NMR) spectra of the various N-vinylarylamines were recorded and chemical shift assignments were made for the first time. The vinyl protons of the enamines generally exhibit an ABX pattern. The electron-rich monomers are sensitive to acid-catalyzed hydrolysis in a wet solvent. Polymerizations of the monomers were carried out at low temperatures with phosphorous pentafluoride as an initiator. It was found that PF5 generated directly from thermal decomposition of p-chlorobenzenediazonium hexafluorophosphate is useful in the preparation of an extremely high-molecular-weight poly(N-vinylcarbazole) (Mw = 3 × 106) with a narrow molecular weight distribution (MWD = 2.1). The polymerizability of N-vinylarylamines appears to vary with the amine functional groups of the monomers. N-vinylarylamine containing a planar amine moiety such as carbazole forms a higher-molecular-weight polymer than the monomers with the nonplanar bulky amine groups.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 7 (1969), S. 1489-1496 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 14C-tagged triphenylmethyl hexachloroantimonate was used to initiate the polymerization of THF. An activity count on the polymers indicated no incorporation of initiator fragments into the macromolecule. On ascertaining the fate of the tagged trityl fragment it was found that the activity resided in the triphenylmethane isolated from the methanol supernatant. This indicates that at least one sequence of the initiation reaction in this polymerization involves hydride ion abstraction.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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