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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 5 (1972), S. 656-657 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 17 (1979), S. 3797-3810 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Several N-vinylarylamines have been prepared by direct N-vinylation of arylamine salts with acetylene at atmospheric pressure. Nuclear magnetic resonance (NMR) spectra of the various N-vinylarylamines were recorded and chemical shift assignments were made for the first time. The vinyl protons of the enamines generally exhibit an ABX pattern. The electron-rich monomers are sensitive to acid-catalyzed hydrolysis in a wet solvent. Polymerizations of the monomers were carried out at low temperatures with phosphorous pentafluoride as an initiator. It was found that PF5 generated directly from thermal decomposition of p-chlorobenzenediazonium hexafluorophosphate is useful in the preparation of an extremely high-molecular-weight poly(N-vinylcarbazole) (Mw = 3 × 106) with a narrow molecular weight distribution (MWD = 2.1). The polymerizability of N-vinylarylamines appears to vary with the amine functional groups of the monomers. N-vinylarylamine containing a planar amine moiety such as carbazole forms a higher-molecular-weight polymer than the monomers with the nonplanar bulky amine groups.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 18 (1980), S. 2869-2873 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 23 (1985), S. 1579-1587 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dark blue poly(copper 2,3,9,10,16,17,23,24-octacyanophthalocyanine) has been prepared by reacting 1,2,4,5-tetracyanobenzene with cuprous chloride in 1-methyl-2-pyrrolidone at ca. 150°C. The product has been characterized by elemental analysis, thermal analysis, infrared and UV-VIS spectroscopies. The polymer has high purity and exhibits good thermal stability in an inert atmosphere.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 23 (1985), S. 1589-1597 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Thermal treatment of novel poly(copper 2,3,9,10,16,17,23,24-octacyanophthalocyanine), PCOCP, has been carried out at different temperatures in an inert atmosphere. As polyacrylonitrile, the polymer can be thermally cyclized through the cyano groups to produce semiconductive and conductive materials. Polymeric copper octacyanophthalocyanine material with a conductivity as high as 5-8 (Ω cm)-1 was prepared. Weight loss, electrical data, infrared, and photoacoustic results of the thermally treated copper octacyanophthalocyanine polymer are discussed.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 33 (1987), S. 657-667 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polypentafluorostyrene (PPFS), polymethylacrylate (PMA), and poly(pentafluorostyrene-co-methylacrylate), poly(PFS-co-MA) were prepared and the wetting characteristics of polymer blends of PPFS and PMA were compared with that of poly(PFS-co-MA) via contact angle measurements. The critical surface tension of polypentafluorostyrene was found to be 22.6 dyne/cm, which is comparable to the value reported for polytrifluoroethylene (22 dyne/cm). The critical surface tension of poly(PFS-co-MA) is not linearly related to its composition. The polymer blends of PPFS and PMA exhibit significant surface enrichment of the fluoropolymer. The harmonic-mean method1 was employed to determine surface tensions of these polymers and many known polymers. It is found that the method produces useful surface tension data provided the contact angle values are derived from testing liquids of dissimilar polarity.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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