ISSN:
0021-8995
Schlagwort(e):
Chemistry
;
Polymer and Materials Science
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
,
Maschinenbau
,
Physik
Notizen:
Attempts have been made to demonstrate the involvement of free radicals in the benzthiazolesulfenamide-accelerated vulcanization of natural rubber. Free radicals were only detected by ESR in reaction mixtures containing the retarder N-nitrosodiphenylamine (NDPA). In addition, NDPA was the only compound found, from the vulcanization accelerator and retarders tested, to affect the free-radical polymerization of methyl methacrylate. A purely ionic mechanism for sulfur vulcanization of natural rubber accelerated by benzthiazolesulfenamide derivatives has therefore been assumed and used to help in the design of new vulcanization retarders. A new class of retarder has been discovered, consisting of hydrocarbylthio derivatives of trisalkylsulfonyl methane. These retarders are believed to be the first vulcanization retarders to act by cleavage of a carbon-sulfur bond.
Zusätzliches Material:
4 Tab.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/app.1972.070161017
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