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  • 1965-1969  (26)
  • 1960-1964  (27)
  • Inorganic Chemistry  (38)
  • Polymer and Materials Science  (15)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 323 (1963), S. 57-64 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The degree of electric charging of metal surfaces due to retarding of neutral metallic and semiconducting particles having various velocities has been determined. The effects are supposed to result from the exo-emission of electrons the amount of which depends on the velocities, masses, and impact angles of the particles.From the strong differences between the reactivities of solid substances during and after mechanical working it is concluded that the observed exo-emission is caused by exitation states at submicroscopic surface points.
    Notes: Die elektrische Aufladung von Metalloberflächen bei der Impuls-Bremsung nicht geladener, fliegender, metallischer und halbleitender Partikel verschiedener Geschwindigkeiten wird gemessen. Die beobachteten Erscheinungen lassen sich aus der Exo-Emission von Elektronen herleiten. Diese ergibt sich u. a. aus dem Zusammenhange zwischen der Elektronen-Austrittsarbeit der beteiligten Partner und der Größe der gebremsten Impulse. Die Ladungs-Übergänge hängen Übersichtlich vom Quadrat der Geschwindigkeiten, von der Masse und vom Auftreffwinkel der Körner ab. Einflüsse mechanischer Vorbehandlung der Festkörper, entsprechend früheren Beobachtungen, werden bestätigt.Im Zusammenhange mit den beobachteten großen Unterschieden des Reaktionsvermögens von Festkörpern während der Bearbeitung und nach ihrem Abschluß lassen die beobachteten Exo-Emissionen auf das Auftreten erhöhter Anregungszustände an submikroskopischen Orten während der Impuls-Bremsung schließen.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 11 (1960), S. 601-616 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Flame spraying of aluminaCeramic coatings produced by the flame spraying process are intended to protect the basic material against corrosion, erosion and oxidation as well as to act as a thermal barrier. For this purpose, alumina was found to be particularly well suited because of its high melting point, hardness, chemical resistance and other favourable properties. With this material as a model substance, the basic processes encountered with the spraying of ceramic powders have been investigated. The investigations comprised the melting process in the flame jet, the composition, lattice structure and physical properties of the spray coating, and the adhesion of the latter on pure metals and alloys with different surface roughness conditions.Although the porosity of these coatings is small, it prevents them from offering complete protection against corrosion and oxidation. But the protection effect can be enhanced by using resistant intermediate metal or enamel layers, and by stabilizing the sprayed coating. Owing to their high abrasion resistance and thermal barrier effect, these coatings have already found a wide field of application.
    Notes: Nach dem Flammspritzverfahren hergestellte keramische Überzüge haben die Aufgabe, das Grundmaterial gegen Korrosion, Erosion and Oxydation zu schützen sowie als Wärmeschranke zu wirken. Besonders geeignet erweist sich hierfür Aluminiumoxyd wegen seines hohen Schmelzpunktes, seiner Härte, seiner chemischen Resistenz und anderer günstiger Eigenschaften. Mit diesem Material als Modellsubstanz wurden die grundlegenden Vorgänge beim Spritzen von Keramik-Pulvern verfolgt. Die Untersuchungen erstreckten sich auf den Schmelzvorgang im Flammstrahl, auf den Aufbau, die Gitterstruktur und die physikalischen Eigenschaften der Spritzschicht sowie auf deren Haftung auf Reinmetallen und Legierungen mit verschiedener Oberflächenaufrauhung.Die Überzüge bieten wegen ihrer, wenn auch geringen Porosität keinen vollständigen Schutz gegen Korrosion und Oxydation. Durch Verwendung von resistenten Zwischenschichten aus Metall oder Email und durch Stabilisierung der Spritzschicht kann die Schutzwirkung jedoch erhöht werden. Auf Grund ihrer Abriebfestigkeit und ihrer wärmedämmenden Wirkung haben die Überzüge bereits ein weites Anwendungsgebiet gefunden.
    Additional Material: 19 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 15 (1964), S. 51-58 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Application of large-diameter pipes made of hard polyethyleneWith the aid of numerous illustrations, the applications of polyethylene pipes of relatively large diameters are surveyed. A special account is given of the advantages which such pipes may offer under different installation conditions. Especially in the Scandinavian countries  -  Norway, Finland and Sweden  -  where pipes are laid in the open even during the winter months, the toughness of hard polyethylene, even at low temperatures, is found to be a particular advantage. A special problem is posed by the need for a reliable jointing of large-diameter pipes. It is shown that, if the necessary conditions are adhered to, and if suitable aids are used, it is possible to obtain reliable butt welds, both between one pipe and another, and between pipe and welding collar. Such welding collars can be made in different ways. For instance, a mould is filled with the aid of an extruder and a rough cast prepared which, after cooling, is machined on a lathe. Pipes made of hard polyethylene are used not only for drinking water pipes but also for special purposes, e. g. cable protection pipes. For this purpose, a special technique, known as jetting method, is sometimes used for laying pipes across water.
    Notes: Anhand einer großen Anzahl van Bildern wird über den Einsatz van Rohren relativ großen Durchmessers aus Hart-Polyäthylen berichtet. Dabei wird auch auf die Vorteile, die solche Rohre unter den verschiedensten Verlegebedingungen bieten, näher eingegangen. Gerade in skandinavischen Ländern wie Norwegen, Finnland und Schweden, wo auch während der Wintermonate Rohrverlegungen im Freien stattfinden, erweist sich die gute Zähigkeit von Hart-Polyäthylen auch in der Kälte von besonderem Vorteil. Ein besonderes Problem stellt die zuverlässige Verbindung von Rohren großen Durchmessers der. Es wird gezeigt, daß bei Einhaltung der erforderlichen Bedingungen und bei Verwendung geeigneter Hilfsgeräte einwandfreie Stumpfschweißungen sowohl der Rohre untereinander als auch von Rohr und Vorschweißbund erzielt werden können. Die Herstellung solcher Vorschweißbunde kann auf verschiedene Arten vorgenommen werden; z. B. wird mit Hilfe eines Extruders eine Form gefüllt und durch Pressen ein Rohling hergestellt, der nach dem Erkalten auf einer Drehbank bearbeitet wird. Neben der Verwendung van Rohren aus Hart-Polyäthylen für Trinkwasserleitungen werden sie auch für Spezialzwecke, wie z. B. Kabelschutzrohre, eingesetzt. Dabei wird in manchen Fällen eine besondere Verlegetechnik beim Durchqueren van Gewässern, das sog. Einspülverfahren, angewandt.
    Additional Material: 36 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 8 (1964), S. 1869-1888 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Graft polymers of acrylonitrile, methacrylonitrile and methyl methacrylate on polyhydroxy polymers such as cellulose and polyvinyl alcohol were prepared by anionic graft polymerization. The alkali alkoxide derivative of the polyhydroxy polymer backbone was used as initiator of polymerization. The graft polymerizations were carried out in liquid ammonia and other inert solvents at low temperature. Grafting was accompanied by considerable homopolymerization caused by chain transfer to monomer and to ammonia. The graft polymers were separated from homopolymers and unreacted polyhydroxy polymers by extraction with suitable solvents. The per cent of the grafted vinyl polymer increased with increase in the monomer and alkoxide concentration. No crosslinking occurred during the anionic graft polymerization, and soluble graft polymers were obtained.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 12 (1968), S. 1803-1805 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 13 (1969), S. 721-744 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Although sulfonium salts are well known, polymeric sulfonium salts seldom have been mentioned in the chemical literature. This paper describes exploratory work in the preparation of various sulfonium monomers and polymers from ar-vinylbenzyl chlorides (ortho and para isomers). These chlorides - particularly the para isomer - reacted readily with 2,2′-thiodiethanol and water to yield the corresponding ar-vinylbenzyl sulfonium chloride monomers in aqueous solution. The odorless, reactive monomer mixture polymerized readily with persulfate or hydroperoxide catalysts; however, polymerization could be inhibited with cupric salts. Copolymerization with trimethyl(ar-vinylbenzyl)ammonium chloride was random. In copolymerization with acrylamide or acrylonitrile, the sulfonium monomer was more reactive. Analogous sulfonium monomers were made by reaction of ar-vinylbenzyl chlorides with various sulfides. In general, all the sulfonium monomers yielded homopolymers which were fairly stable in aqueous solution in the absence of strongly nucleophilic agents which would attack the sulfonium groups. However, when dried at room temperature the polymers would crosslink; and when heated, the polymers became hydrophobic also. Scrambling of the sulfonium group substituents during drying, and nucleophilic displacement reactions by chloride ion during heating were likely explanations. The high cationic charge on the polymers made them substantive to cellulose fibers. This property, when coupled with high nucleophilic reactivity of the sulfonium groups with the carboxylate sites of the pulp or other anionic counterious during drying and heating, made the polymers very effective as beater additives for imparting wet strength to paper.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 7 (1963), S. 783-787 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Monomers of vinyl formate, vinyl acetate, vinyl propionate, and vinyl butyrate were carefully purified by distillation in a Vigreux column and in a 56-plate glass helixpacked Todd column. The refractive indices and boiling points of the purified monomers agreed with those given in the literature. The purified samples were exposed to the radiation of a quartz mercury lamp in order to produce several per cent polymer. The refractive indices are tabulated and plotted in graphs.
    Additional Material: 4 Ill.
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  • 8
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 338 (1965), S. 90-99 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Mechanical working of Ni crystals leads to surface deformations being typical for c. f. c. lattices. By interaction with H2S (formation of NiS), a chemical decoration of the gliding strips is possible which allows, by means of normal and electron microscope techniques, to study the mechanochemically activated surface areas of single- and polycrystalline Ni. Annealing after the mechanical working results first in a decrease of the chemical activity and then, at sufficiently high temperatures, in a complete loss of activity and chemical decoration.
    Notes: Bei der mechanischen Bearbeitung von Ni-Kristallen entstehen auf der Oberfläche die für kubisch-flächenzentrierte Kristalle typischen Deformationsstrukturen. Ausgehend von den Vorstellungen über erleichterte Keimbildungsbedingungen in Bereichen hoher Spannungskonzentration, in denen hohe Versetzungsdichten auftreten, lassen sich die entstehenden Gleitbänder durch H2S-Einwirkung unter Bildung von Nickelsulfid auf chemischem Wege dekorieren. Unter Anwendung mikroskopischer und elektronenmikroskopischer Methoden werden mit diesem Verfahren die bei der mechanischen Beanspruchung von Einkristallen und Polykristallen auftretenden Störbereiche nachgewiesen. Die Temperung der Kristalle nach Abschluß der mechanischen Bearbeitung führt zu einer Abnahme der Aktivität. Bei genügend hohen Temperaturen geht schließlich die selektive Reaktion an Gleitbändern vollständig verloren und führt zu einem Verlust des Dekorationseffektes.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 313 (1961), S. 107-116 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The GRIGNARD reaction between silicon halides and alkyl-Mg-halides with steric hindering alkyl groups does not run in the usual manner. Thus from SiBr4 and secondary or tertiary butyl—MgBr only the corresponding butyl-tribromosilanes (C4H9)SiBr3 could be prepared in low yields. To a great extent, there are side reactions which produce silanes with Si—H-bonds by developing butene (C4H8) and high molecular polysilanes with, Si—Si-bonds by cleaving off octane (C8H18).
    Notes: Die Grignard-Reaktion zwischen Silicium-halogeniden und Alkyl-Mg-halogeniden mit sterisch hindernden Alkylgruppen verläuft anormal. So konnten aus SiBr4 und sekundärem oder tertiärem Butyl—MgBr nur die entsprechenden Butyl-tribrom-silane (C4H9)SiBr3 in geringen Ausbeuten gewonnen werden. Es finden in großem Umfange Nebenreaktionen statt, die unter Abspaltung von Buten(C4H8) zu Silanen mit Si—H-Bindungen, sowie unter Entwicklung von Octan (C8H18) zu hochmolekularen Polysilanen mit Si—Si-Bindungen führen.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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