ISSN:
0018-019X
Schlagwort(e):
Chemistry
;
Organic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The fragmentation of 4-bromo-quinuclidine (7) to N,4-bis-methylene-piperidinium bromide (8) has been studied in six solvents. In 80% ethanol and in 70% dioxane 4-bromo-quinuclidine reacts 5.5 · 104 times as fast as the homomorphous compound 1-bromo-bicyclo[2.2.2]octane (9). The nitrogen atom therefore participates in the rate determining step.
Zusätzliches Material:
3 Tab.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/hlca.19650480116
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