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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 263 (1985), S. 328-334 
    ISSN: 1435-1536
    Keywords: Melt rheology ; network transition ; molecular weight distribution ; Doi-Edwards theory
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The molecular theory proposed by Doi and Edwards is applied to the determination of the rheological behaviour of a technical polystyrene with medium molecular weight and rather broad molecular weight distribution. The molecular parameters of the polystyrene were measured by means of the GPC method. The rheological properties of the sample were investigated by means of a dynamic viscometer. It is shown that a good description of the linear viscoelastic properties of the melt of the polystyrene can be given using the Doi-Edwards theory combined with a mixing rule of simple superposition of the moduli according to the number fractions of the molecular weights.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 14 (1975), S. 581-590 
    ISSN: 1435-1528
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Zusammenfassung Numerische Formeln werden gegeben, die die Berechnung des Spannungsrelaxationsmoduls aus dem dynamischen Modul ermöglichen. In diesen Formeln treten Werte des Speichermoduls und Verlustmoduls auf, die bei logarithmisch äquidistanten Frequenzen gemessen wurden. Das Verhältnis zweier aufeinanderfolgender Frequenzen entspricht stets einem Faktor 2. Für alle Formeln werden obere und untere Schranken für den relativen Fehler abgeleitet. Diese Schranken hängen vom Werte der Dämpfung (tanδ) ab, die bei der Kreisfrequenzω 0 auftritt, für die die Berechnung erfolgt. Die Berechnung des Relaxationsmoduls ist um so einfacher, je niedriger der Wert der Dämpfung ist. Zu dieser Berechnung benötigt man entweder den Wert des Speichermoduls bei der Kreisfrequenzω 0=1/t und die Werte des Verlustmoduls in einem ziemlich engen Frequenzintervall umω 0, oder den Wert des Speichermoduls bei der Kreisfrequenzω 0 und den Wert der logarithmischen Frequenzableitung des Speichermoduls in einem Frequenzintervall umω 0.
    Notes: Summary Numerical formulae are given for calculation of stress relaxation modulus from the known course of the storage and loss modulus with frequency for linear viscoelastic materials. The formulae involve values of the storage modulus and/or loss modulus at frequencies equally spaced on a logarithmic frequency scale, the ratio between successive frequencies beeing two. A method is introduced by which bounds for the relative errors of these formulae can be derived. These bounds depend on the value of the damping, tanδ, at the angular frequency,ω, for which the calculation is made. The less the damping, the simpler the calculation of the stress relaxation modulus. This calculation involves either the value of the storage modulus at a frequencyω 0 = 1/t, and the values of the loss modulus in a rather narrow frequency region aroundω 0, or the value of the storage modulus at frequencyω 0 and the derivative of the storage modulus with respect to the logarithm of frequency in a frequency region aroundω 0.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 1 (1961), S. 345-355 
    ISSN: 1435-1528
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Zusammenfassung Verschiedene makroskopische Theorien des rheologischen Verhaltens werden miteinander verglichen. Die physikalischen Grundgedanken dieser Theorien werden erörtert und es wird auf die Bedeutung hingewiesen, die diese Theorien im Laufe des letzten Jahrzehntes für die Beschreibung des mechanischen Verhaltens hochpolymerer Stoffe gewonnen haben.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 30 (1991), S. 300-300 
    ISSN: 1435-1528
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 26 (1987), S. 375-384 
    ISSN: 1435-1528
    Keywords: Torsional creep ; creep recovery ; time-temperaturesuperposition ; recoverable compliance ; polystyrene
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract The torsional creep and recoverable bahaviour of a technical polystyrene is reported over seven orders of magnitude of the value of the compliance from 10−8 to 10−1 Pa−1 and over more than seven decades in time. The results for the recoverable compliance JR (t) reveal a dispersion region seen between the glass transition and the steady-state recoverable compliance Je. The limiting value of the final dispersion Je = 4.7 · 10−4 Pa−1 indicates a broad molecular-weight distribution. The steady-state recoverable compliance Je is independent of the temperature. The temperature dependence of the final dispersion was found to be indistinguishable from that of viscous flow. However, this temperature dependence differs significantly from that of the glass-rubber transition. A proposal has been made for the construction of creep compliance and recoverable compliance over an extended time scale.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 148 (1956), S. 47-57 
    ISSN: 1435-1536
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Zusammenfassung Es wird das lineare viskoelastische Verhalten isotroper Materialien unter dreidimensionalen Spannungszuständen behandelt. Die Grundlage der Theorie ist ein verallgemeinertes Superpositionsprinzip, aus dem sich der Spannungszustand berechnen läßt, wenn der Deformationszustand und seine Vorgeschichte bekannt sind, oder der Deformationszustand, wenn der Spannungszustand und seine Vorgeschichte bekannt sind. Als charakteristische, zeitabhängige Materialfunktionen kommen in Frage: 1. Die Kriechfunktionen (Nachgiebigkeiten) bei einfacher Scherung, isotroper Kompression und einfacher Dehnung:J(t), B(t) undF(t) (monoton wachsende Funktionen der Zeit). 2. Die Spannungsrelaxationsmoduli bei einfacher Scherrung, isotroper Kompression und einfacher Dehnung:G(t), K(t) undE(t) (monoton abnehmende Funktionen der Zeit). 3. Ein zeitabhängiges Poissonsches Verhältnisv(t). Zwei dieser charakteristischen Materialfunktionen — gehörig zu Experimenten verschiedener geometrischer Typen — sind ausreichend zur vollständigen Beschreibung des mechanischen Verhaltens. Alle anderen charakteristischen Funktionen können dann daraus abgeleitet werden. Sowohl der Scherungsmodul G(t), als auch der KompressionsmodulK(t) können eine Reihe voneinander unabhängiger Dispersionsgebiete aufweisen. Ein Dispersionsgebiet im Scherungsmodul ohne ein zugehöriges Dispersionsgebiet im Kompressionsmodul führt zu einem Ansteigen des Poissonschen Verhältnisses. Der bis jetzt noch nicht experimentell gefundene Fall eines Dispersionsgebietes im Kompressionsmodul ohne ein zugehöriges Dispersionsgebiet im Scherungsmodul führt zu einem Absinken des Poissonschen Verhältnisses. Haben Scherungsmodul und Kompressionsmodul dieselbe „Relaxationsstärke“, so bleibt das Poissonsche Verhältnis konstant. Aus dem heutzutage bekannten experimentellen Tatsachenmaterial an Hochpolymeren erwarten wir, daß ein Übergangsgebiet im Scherungsmodul von einem Ansteigen des Poissonschen Verhältnisses und möglicherweise von einer schwachen Dispersion des Kompressionsmoduls begleitet wird.
    Notes: Abstract The linear viscoelastic behaviour of isotropic materials under three dimensional stress distributions is treated by means of a generalised superposition principle, which yields the state of stress under known strain history and vice versa. The material is completely characterised mechanically, if two independent characteristic material functions are determined. As such we may choose: 1. the creep compliances in simple shear, isotropic compression and linear extensionJ(t), B(t) andF(t) (monotonously increasing functions of time). 2. the stress relaxation moduli in simple shear, isotropic compression and linear extensionG(t), K(t) andE(t) (monotonously decreasing functions of time), 3. a time dependent Poisson's ratiov(t) (varying unrestrictedly between 0 and 1/2). The relationships between these functions are given. The shear modulusG(t) as well as the bulkK(t) may show independent dispersion regions. A dispersion in the shear modulus without dispersion in the bulk modulus leads to an increase in Poisson's ratio, a dispersion in the bulk modulus without dispersion in the shear modulus would lead to a decrease in Poisson's ratio. If the “relaxation strengths” in shear modulus and bulk modulus are equal, Poisson's ratio remains constant. From the consideration of the experimental facts on high polymers known to day, it is emphasized that a transition region in shear modulus will generally be accompanied by an increase in Poisson's ratio and may perhaps be followed by a slight relaxation of the bulk modulus.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 252 (1974), S. 759-759 
    ISSN: 1435-1536
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Physica 18 (1952), S. 791-798 
    ISSN: 0031-8914
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Physica 17 (1951), S. 923-929 
    ISSN: 0031-8914
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Physica 17 (1951), S. 830-840 
    ISSN: 0031-8914
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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