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Polymers of acetylenic nitriles (1965)

Lee, S. M.

New York, NY [u.a.] : Wiley-Blackwell

Journal of Applied Polymer Science 9 (1965), S. 1431-1435

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ISSN: 0021-8995

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics

Notes: Efforts to prepare 1,6-dicyano-2,4-hexadiyne resulted in the formation of insoluble, chemically inert, high-melting “brick dust” type polymeric materials. Similar appearing products arose from the dihalo-, ditosyl-, and dihydroxy- hexadiyne derivatives as well as propargyl halide starting materials. It appears that diacetylenic diols and their propargylic precursors undergo direct nitrilation.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/app.1965.070090419

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