ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
TiCl3 bildet mit 2,2′-Dipyridyl einen 1:2-Komplex, der in Substanz isoliert und konduktometrisch, potentiometrisch sowie analytisch untersucht wurde. Auf Grund der Beobachtung, daß nur eines der drei Chloratome in wäßriger Lösung als Cl- abdissoziiert, wird ein Strukturvorschlag gemacht.
Notes:
Titanium(III) chloride was found to undergo complex formation with 2.2′-dipyridyl producing a white crystalline compound. The composition of the complex in solution was found to be in the molar ratio of 1:2 (titanium:dipyridyl) by conductometric and potentiometric titrations. The complex was also recrystallised, and its analysis confirmed the results of the titrations. The complex was found to yield a single free chloride ion in solution. A possible structure of the complex is proposed.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19653360116
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