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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 392 (1972), S. 316-320 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Komplexe von Thoriumtetrachlorid und Uranylsulfat mit Phenylhydrazin und BenzidinPhenylhydrazin (Ph) und Benzidin (B) bilden mit Thoriumtetrachlorid und Uranylsulfat Komplexe der Formeln [ThPh4]Cl4, [ThB2Cl2]Cl2, [UO2Ph]SO4 und [UO2B(THF)]SO4 (THF = Tetrahydrofuran). Die Verbindungen werden isoliert, analysiert und ihre Leitfähigkeiten in Dimethylsulfoxid und Dimethylformamid gemessen. Die Art der Koordination wird auf Grund der IR-Spektren diskutiert.
    Notes: Phenyl hydrazine (Ph) and benzidine (B) form complexes with thorium tetrachloride and uranyl sulphate of the general composition correspond to: [ThPh4]Cl4, [ThB2Cl2]Cl2, [UO2Ph]SO4 and [UO2B(THF)]SO4 (THF = tetrahydrofuran). The compounds were isolated, analysed and their molar conductivities were determined in dimethyl sulphoxide and dimethylformamide. The nature of coordination was discussed in the light of i.r. spectral assignments.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 336 (1965), S. 110-112 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: TiCl3 bildet mit 2,2′-Dipyridyl einen 1:2-Komplex, der in Substanz isoliert und konduktometrisch, potentiometrisch sowie analytisch untersucht wurde. Auf Grund der Beobachtung, daß nur eines der drei Chloratome in wäßriger Lösung als Cl- abdissoziiert, wird ein Strukturvorschlag gemacht.
    Notes: Titanium(III) chloride was found to undergo complex formation with 2.2′-dipyridyl producing a white crystalline compound. The composition of the complex in solution was found to be in the molar ratio of 1:2 (titanium:dipyridyl) by conductometric and potentiometric titrations. The complex was also recrystallised, and its analysis confirmed the results of the titrations. The complex was found to yield a single free chloride ion in solution. A possible structure of the complex is proposed.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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