Library

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • 1960-1964  (308)
  • 1945-1949  (160)
  • Organic Chemistry  (468)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 44 (1961), S. 299-309 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Four 2,4-disubstituted 6,7-dihydro-imidazo[1,2-a]-s-triazines (IV, VII, X and XV) have been synthesized according to the following scheme: (a) monosubstitution of cyanuric chloride (I) with ethanolamine, (b) replacement of the remaining chlorine atomes by suitable groupe, and (c) cyclisation of the 2′-hydroxy-ethylamino side chain on one of the adjacent cyclic nitrogen atoms of the s-triazine nucleus. This last step includes reaction of the 2-[(2-hydroxy-ethyl)-amino]-s-triazines with thionyle chloride or p-toluenesulfonyl chloride and, with one exception (VIII→IX), heating the resulting 2-[(2-chloro-ethyl)-amino] derivatives or p-toluenesulfonic esters in a solvent.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 16 (1962), S. 251-257 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The reactions between aluminium alkoxides (methoxide, ethoxide, isopropoxide, n, sec. and tert. butoxides) and acetyl bromide has been studied and the compounds of the type: AlBr(OR)2, Al(OR)Br2 · 0.5 CH3COOR and AlBr3 · 1.5 CH3COOR, where OR is OMe, OEt, OPri, n, sec. or tert. OBu, have been isolated. The reaction of aluminium tert. butoxide and acetyl bromide was found to be very slow in cold as well as in boiling condition. The above compounds were crystallised from their respective alcohols, whereever possible. The ease with which these compounds exchange their radicals has been demonstrated by the reaction between tri-bromide and mono-bromide di-isopropoxide, in isopropanol, whereby the di-bromide was crystallised out. These bromide alkoxides are not stable to heat, even under reduced pressure.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 105-112 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The reactions of aluminium isopropoxide and aluminium chloride with salicylic, mandelic and lactic acids in different stoichiometric ratios have been studied under absolutely anhydrous conditions. Mandelic and lactic acids were found to give tri-derivatives, whereas the salicylic acid gave only di-salicylate when the ratios of alkoxide and the acid was 1:3 (or slightly higher) or an equimolecular mixture of di-and tri-salicylate when the ratio was increased to 1:3.4 (or 3.4).
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 44 (1961), S. 213-231 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Different methods have been investigated for the preparation of N-CBO-S-benzyl- L-cysteinyl-N-methyl-L-tyrosyl-L-isoleucine. Condensation of this protected tripeptide with L-glutaminyl-L-asparaginyl-S-benzyl-L-cysteinyl-L-prolyl-L-leucyl-glycinamide affords N-CBO- S -benzyl-L-cysteinyl-N -methyl-L-tyrosyl-L-isoleucyl-L-glutaminyl-L- asparaginyl-S-benzyl-L-cysteinyl-L-prolyl-L-leucyl-glycinamide. Cleavage of the protecting groups of the resulting nonapeptide with sodium in liquid ammonia, oxidation with air in dilute aqueous solution and purification by counter-current distribution gives the desired cyclic nonapeptide amide : (N-methyl-Tyr)2-oxytocin. This exhibits less than one per cent of the oxytocic potency of oxytocin.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 5
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dans le but d'établir la polytherme de saturation du système ternaire Ca++—NH4+—NO-—H2O entre 0° et 75°, nous avons effectué de nombreuses déterminations de solubilité aux températures de O°, 20°, 35°, 40°, 50° et 75°.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 6
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 46 (1963), S. 1669-1676 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Orn8-vasopressin and Orn8-oxytocin have been synthesized and their biological activities compared with those of arginine-vasopressin and lysine-vasopressin and of arginine-vasotocin and lysine-vasotocin, respectively. The replacement of the arginine or lysine residues by an ornithin residue to not considerably affect the oxytocic and pressorie activities.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 7
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 45 (1962), S. 1146-1152 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Structure X:R = H2 has been derived for the alkaloid kopsine from chemical and spectroscopic evidence and by a correlation with the alkaloid pleiocarpine (IX: R = R1 = COOCH3; R2 = H2). Structures XI: R = H2; R1 = OH; R2 = H and XI: R = H2; R1 = H; R2 = OH, respectively, represent dihydrokopsine-A and dihydrokopsine-B.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 8
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 43 (1960), S. 182-190 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: N-CBO-L-Glutaminyl-L-asparaginyl-S-benzyl-L-cysteinyl-azide has been condensed with L-prolyl-∊-N-tosyl-L-lysyl-glycinamide, giving N-CBO-L-glutaminyl L-asparaginyl-S-benzyl-L-cysteinyl-L-prolyl∊-N-tosyl-L-lysyl-glycinamide, which after spliting of the CBO-protecting group has been condensed with N-CBO-S-benzyl-L-cysteinyl-L-tyrosyl-L-isoleucyl-azide. Cleavage of the protecting groups of the resulting nonapeptide with sodium in liquid ammonia, oxidation with air in dilute aqueous solution and purification by counter-current distribution afforded Lys8-oxytocin, which represents a structural intermediate between oxytocin and lysine-vasopressin and which exhibits the biological properties of both these natural hormones.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 9
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 45 (1962), S. 806-809 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Investigations by X-ray and electron diffraction show that sodium chloride will be bound by casein, if the salt is added in aqueous solution to the protein and if the water is then removed under isothermal and nearly reversible conditions. This confirms earlier results obtained by water sorption measurements. The diffraction method is a simple and safe way for determining the maximum salt binding capacity of the protein. 90 to 95 models of NaCl are bound by 105 g of casein, which is more than 80% of the amount calculated from the amino-acid composition of the protein.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 10
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Using a solution of [35S]-phenylisothiocyanate in pentane with a specific activity of 30 to 8O mC/mmole, the authors have determined the sequence of di-, tri-peptides and a pentapeptide on the following quantities: 1 to 2 nmole of peptide when the [35S]-phenylthiohydantoines obtained in each step of EDMAN'S degradation are identified by classical paper chromatography; 0,l to 0,2 nmole of peptide when these [35S]-phenylthiohydantoines are identified by silica thin layer chromatography.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...