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  • 1960-1964  (16)
  • General Chemistry  (11)
  • Polymer and Materials Science  (5)
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Year
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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 11 (1960), S. 601-616 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Flame spraying of aluminaCeramic coatings produced by the flame spraying process are intended to protect the basic material against corrosion, erosion and oxidation as well as to act as a thermal barrier. For this purpose, alumina was found to be particularly well suited because of its high melting point, hardness, chemical resistance and other favourable properties. With this material as a model substance, the basic processes encountered with the spraying of ceramic powders have been investigated. The investigations comprised the melting process in the flame jet, the composition, lattice structure and physical properties of the spray coating, and the adhesion of the latter on pure metals and alloys with different surface roughness conditions.Although the porosity of these coatings is small, it prevents them from offering complete protection against corrosion and oxidation. But the protection effect can be enhanced by using resistant intermediate metal or enamel layers, and by stabilizing the sprayed coating. Owing to their high abrasion resistance and thermal barrier effect, these coatings have already found a wide field of application.
    Notes: Nach dem Flammspritzverfahren hergestellte keramische Überzüge haben die Aufgabe, das Grundmaterial gegen Korrosion, Erosion and Oxydation zu schützen sowie als Wärmeschranke zu wirken. Besonders geeignet erweist sich hierfür Aluminiumoxyd wegen seines hohen Schmelzpunktes, seiner Härte, seiner chemischen Resistenz und anderer günstiger Eigenschaften. Mit diesem Material als Modellsubstanz wurden die grundlegenden Vorgänge beim Spritzen von Keramik-Pulvern verfolgt. Die Untersuchungen erstreckten sich auf den Schmelzvorgang im Flammstrahl, auf den Aufbau, die Gitterstruktur und die physikalischen Eigenschaften der Spritzschicht sowie auf deren Haftung auf Reinmetallen und Legierungen mit verschiedener Oberflächenaufrauhung.Die Überzüge bieten wegen ihrer, wenn auch geringen Porosität keinen vollständigen Schutz gegen Korrosion und Oxydation. Durch Verwendung von resistenten Zwischenschichten aus Metall oder Email und durch Stabilisierung der Spritzschicht kann die Schutzwirkung jedoch erhöht werden. Auf Grund ihrer Abriebfestigkeit und ihrer wärmedämmenden Wirkung haben die Überzüge bereits ein weites Anwendungsgebiet gefunden.
    Additional Material: 19 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 15 (1964), S. 51-58 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Application of large-diameter pipes made of hard polyethyleneWith the aid of numerous illustrations, the applications of polyethylene pipes of relatively large diameters are surveyed. A special account is given of the advantages which such pipes may offer under different installation conditions. Especially in the Scandinavian countries  -  Norway, Finland and Sweden  -  where pipes are laid in the open even during the winter months, the toughness of hard polyethylene, even at low temperatures, is found to be a particular advantage. A special problem is posed by the need for a reliable jointing of large-diameter pipes. It is shown that, if the necessary conditions are adhered to, and if suitable aids are used, it is possible to obtain reliable butt welds, both between one pipe and another, and between pipe and welding collar. Such welding collars can be made in different ways. For instance, a mould is filled with the aid of an extruder and a rough cast prepared which, after cooling, is machined on a lathe. Pipes made of hard polyethylene are used not only for drinking water pipes but also for special purposes, e. g. cable protection pipes. For this purpose, a special technique, known as jetting method, is sometimes used for laying pipes across water.
    Notes: Anhand einer großen Anzahl van Bildern wird über den Einsatz van Rohren relativ großen Durchmessers aus Hart-Polyäthylen berichtet. Dabei wird auch auf die Vorteile, die solche Rohre unter den verschiedensten Verlegebedingungen bieten, näher eingegangen. Gerade in skandinavischen Ländern wie Norwegen, Finnland und Schweden, wo auch während der Wintermonate Rohrverlegungen im Freien stattfinden, erweist sich die gute Zähigkeit von Hart-Polyäthylen auch in der Kälte von besonderem Vorteil. Ein besonderes Problem stellt die zuverlässige Verbindung von Rohren großen Durchmessers der. Es wird gezeigt, daß bei Einhaltung der erforderlichen Bedingungen und bei Verwendung geeigneter Hilfsgeräte einwandfreie Stumpfschweißungen sowohl der Rohre untereinander als auch von Rohr und Vorschweißbund erzielt werden können. Die Herstellung solcher Vorschweißbunde kann auf verschiedene Arten vorgenommen werden; z. B. wird mit Hilfe eines Extruders eine Form gefüllt und durch Pressen ein Rohling hergestellt, der nach dem Erkalten auf einer Drehbank bearbeitet wird. Neben der Verwendung van Rohren aus Hart-Polyäthylen für Trinkwasserleitungen werden sie auch für Spezialzwecke, wie z. B. Kabelschutzrohre, eingesetzt. Dabei wird in manchen Fällen eine besondere Verlegetechnik beim Durchqueren van Gewässern, das sog. Einspülverfahren, angewandt.
    Additional Material: 36 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 8 (1964), S. 1869-1888 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Graft polymers of acrylonitrile, methacrylonitrile and methyl methacrylate on polyhydroxy polymers such as cellulose and polyvinyl alcohol were prepared by anionic graft polymerization. The alkali alkoxide derivative of the polyhydroxy polymer backbone was used as initiator of polymerization. The graft polymerizations were carried out in liquid ammonia and other inert solvents at low temperature. Grafting was accompanied by considerable homopolymerization caused by chain transfer to monomer and to ammonia. The graft polymers were separated from homopolymers and unreacted polyhydroxy polymers by extraction with suitable solvents. The per cent of the grafted vinyl polymer increased with increase in the monomer and alkoxide concentration. No crosslinking occurred during the anionic graft polymerization, and soluble graft polymers were obtained.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 7 (1963), S. 783-787 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Monomers of vinyl formate, vinyl acetate, vinyl propionate, and vinyl butyrate were carefully purified by distillation in a Vigreux column and in a 56-plate glass helixpacked Todd column. The refractive indices and boiling points of the purified monomers agreed with those given in the literature. The purified samples were exposed to the radiation of a quartz mercury lamp in order to produce several per cent polymer. The refractive indices are tabulated and plotted in graphs.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 15 (1964), S. 653-660 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The products of the atmospheric corrosion of some common metalsThe layers of corrosion products formed by atmospheric corrosion upon copper, zinc, and iron are essentially composed of crystallized products most of which have been known as ore minerals; further possible relations of this type are pointed out in Table 2. Upon aluminium, however, amorphous layers are formed which have been little explored so far. The author distinguishes between two different layers: (1) the primary oxide layers (passivation layers), the thickness of which is about 10-7 cm and which are directly and in general with a defined crystallographic orientation (epitaxy) intergrown with the crystallites of the metallic substrate; (2) the secondary layers which are much thicker and the chemical gross composition and phase composition are largely determined by impurities in the atmosphere.
    Notes: Die atmosphärisch gebildeten Korrosionsschichten auf Kupfer, Zink und Eisen sind überwiegend aus kristallisierten Verbindungen aufgebaut, die meist als Erzmineralien bekannt sind; Hinweise auf weitere mögliche Zusammenhänge dieser Art gibt Tafel 2. Auf Aluminium entstehen dagegen amorphe und dementsprechend noch recht wenig aufgeklärte Schichten. Es werden unterschieden: Die nur ˜ 10-7 cm starken, oxidischen Primäurschichten (= Passivierungsschichten), die mit den Kristalliten der Metallunterlage direkt und im allgemeinen kristallographisch orientiert (epitaktisch) verwachsen sind, und darüber die sehr viel dickeren Sekundärschichten, deren bruttochemische und Phasenzusammensetzung weitgehend durch Verunreinigungen der Luft (z. B. SO2) bestimmt wird.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 74 (1962), S. 157-157 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 76 (1964), S. 227-227 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 76 (1964), S. 393-399 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Am Beispiel der Synthese des Nickel(II)-Komplexes des (±)-1.8.8.13.13-Pentamethyl-trans-corrins wird ein synthetischer Zugang zum Verbindungstyp der Corrine aufgezeigt. Durch die mehrfache Verwendung des Triäthyloxonium-tetrafluorborats bietet die Arbeit eine Illustration der präparativen Bedeutung der von H. Meerwein und Mitarbeitern entdeckten Trialkyloxoniumsalze.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 0570-0833
    Keywords: Corrinoids ; Vitamins ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis of the nickel(II) complex of (±)-1,8,8,13,13-pentamethyl-trans-corrin illustrates a synthetic route to the corrin system. Repeated use of triethyloxonium tetrafluoroborate in this synthesis demonstrates the preparative value of the trialkyloxonium salts discovered by Meerwein et al.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 0570-0833
    Keywords: Carbon tetrachloride ; Phosgene ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Carbon tetrachloride can be prepared from phosgene at 300-450°C. The catalysts for the reaction are transition metals of Groups V to VIII deposited on activated charcoal as carrier. Carbon monoxide and chlorine may be used as starting materials instead of phosgene.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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