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  • Analytical Chemistry and Spectroscopy  (3)
  • (Human)  (2)
  • Brillouin and Rayleigh scattering  (2)
  • Fluorescence quenching  (2)
  • 1
    Electronic Resource
    Electronic Resource
    A metastable ion study of the electron impact fragmentation of some substituted 2,6-pyrido-containing crown ethers (1987)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 22 (1987), S. 633-636 
    Details
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Extensive networks of metastable ions link the major peaks in the electron impact mass spectra of two crown ethers containing 2,6-pyrido units. High-resolution mass measurements and the metastable peaks allow the elucidation of the fragmentation pathways. The spectra are influenced more by the presence of aromatic substituents than by the 2,6-pyrido units.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/oms.1210220911
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Hb F-Forest Park, a new ^Aγ variant with two amino acid substitutions, 75(E19)Ile -〉 Thr and 73(E17)Asp -〉 Asn, which can be identified in adults by gene-mapping analysis
    Amsterdam : Elsevier
    Biochimica et Biophysica Acta (BBA)/Protein Structure and Molecular 832 (1985), S. 242-247 
    Details
    ISSN: 0167-4838
    Keywords: (Human) ; Amino acid substitution ; Gene mapping ; Hemoglobin variant ; Reverse-phase HPLC
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology , Medicine
    Type of Medium: Electronic Resource
    URL: http://linkinghub.elsevier.com/retrieve/pii/0167-4838(85)90256-0
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Induction of aromatase gene expression in human placental choriocarcinoma (JAR) cells by phorbol esters
    Amsterdam : Elsevier
    Biochimica et Biophysica Acta (BBA)/Gene Structure and Expression 1218 (1994), S. 48-54 
    Details
    ISSN: 0167-4781
    Keywords: (Human) ; Aromatase ; Aromatase expression ; Phorbol ester
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology , Medicine , Physics
    Type of Medium: Electronic Resource
    URL: http://linkinghub.elsevier.com/retrieve/pii/0167-4781(94)90099-X
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    Paper (German National Licenses)
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  • 4
    Electronic Resource
    Electronic Resource
    Selective fluorescence quenching of polynuclear aromatic hydrocarbons in microcolumn liquid chromatography
    Amsterdam : Elsevier
    Analytica Chimica Acta 246 (1991), S. 65-74 
    Details
    ISSN: 0003-2670
    Keywords: Fluorescence quenching ; Liquid chromatography ; Polynuclear aromatic hydrocarbons
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://linkinghub.elsevier.com/retrieve/pii/S0003-2670(00)80665-0
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    Paper (German National Licenses)
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  • 5
    Electronic Resource
    Electronic Resource
    Selective fluorescence quenching of polynuclear aromatic hydrocarbons in microcolumn liquid chromatography
    Amsterdam : Elsevier
    Analytica Chimica Acta 246 (1991), S. 65-74 
    Details
    ISSN: 0003-2670
    Keywords: Fluorescence quenching ; Liquid chromatography ; Polynuclear aromatic hydrocarbons
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1016/S0003-2670(00)80665-0
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    Paper (German National Licenses)
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  • 6
    Electronic Resource
    Electronic Resource
    Small-angle light scattering in dense microemulsions, transition from droplet to bicontinuous phase (1994)
    Springer
    Il nuovo cimento della Società Italiana di Fisica 16 (1994), S. 1627-1633 
    Details
    ISSN: 0392-6737
    Keywords: Brillouin and Rayleigh scattering ; Liquids ; Emulsions and suspensions ; Order-disorder and statistical mechanics of model systems ; Conference proceedings
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Summary We have performed extensive small-angle light scattering (SALS) measurements on a three-component microemulsion (AOT/decane/water) as a function of the dispersed phase concentration and the temperature. All samples have a water/AOT molar fractionw=40.8. Such a system presents a very complex phase diagram with many structural configurations. With the SALS technique, we have been able to observe all the phase separation lines. In particular we give details on the system structure on the percolation phenomenon and on the bicontinuous phase recently observed. In particular we show that the percolation is driven by a long-scale aggregation between microemulsion droplets.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02462051
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  • 7
    Electronic Resource
    Electronic Resource
    Small-angle light scattering studies of dense AOT-water-decane microemulsions (1996)
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 1317-1332 
    Details
    ISSN: 0392-6737
    Keywords: Brillouin and Rayleigh scattering ; other light scattering ; Emulsions and suspensions ; Specific phase transitions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Summary We have performed extensive studies of a three-component microemulsion system composed of AOT-water-decane (AOT=sodium-bis-ethylhexyl-sulfosuccinate is an ionic surfactant) using small-angle light scattering (SALS). The small-angle scattering intensities are measured in the angular interval 0.001–0.1 radians, corresponding to a Bragg wave number range of 0.14 μm−1〈Q〈〈1.4 μm−1. The measurements were made by changing temperature and volume fraction ϕ of the dispersed phase (water + AOT) in the range 0.05〈ϕ〈0.75. All samples have a fixed water-to-AOT molar ratio,w=[water]/[AOT]=40.8, in order to keep the same average droplet size in the stable one-phase region. With the SALS technique, we have been able to observe all the phase boundaries of a very complex phase diagram with a percolation line and many structural organizations within it. We observe at the percolation transition threshold, a scaling behavior of the intensity data. This behavior is a consequence of a clustering among microemulsion droplets near the percolation threshold. In addition, we describe in detail a structural transition from a droplet microemulsion to a bicontinuous one as suggested by a recent small-angle neutron scattering experiment. The loci of this transition are located several degrees above the percolation temperatures and are coincident with the maxima previously observed in shear viscosity. From the data analysis, we show that both the percolation phenomenon and this novel structural transition are derived from a large-scale aggregation between microemulsion droplets.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02453266
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  • 8
    Electronic Resource
    Electronic Resource
    Quantitative analysis of the molecular species of monosialogangliosides by continuous-flow fast-atom bombardment mass spectrometry (1991)
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 5 (1991), S. 618-621 
    Details
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Negative-ion continuous-flow fast-atom bombardment mass spectroemtry was evaluated asa means for the quantitative analysis of N-acetylneuraminyl-galactosyl-glucosyl ceramide (NeuAc-GM3) and N-acetylgalactosaminyl-(N-acetylneuraminyl)galactosyl-glucosyl-ceramide (NeuAc-GM3). This study was carried out on a 7070-EQ mass spectrometer (VG Analytical, Manchester, UK) using a home-made continuous-flow fast-atom bombardment probe with a mixture of methanol +water+triethanolamine (70:27:3, v/v/v)as the mobile phase. Utilizing 100 ng of acetyl-lysogalactosyl-N-acetylgalactosaminyl-(N-acetylneuraminyl)galactosyl-glucosylceramide (acetyl-lysoGM1) as an internal standard curves for NeuAc-GM3 d18:1-16 0, NeuAc-GM3 d18:1-18:0 and Neuac-GM3 d18:1-18:0 were found to be linear over the range 5-250ng, with associated correlation coefficients of 0.990-0.997. The lower limit of detection was found to be 2.5ng. Satisfactory results could also de obtained when the calibration curves were derived from the deprotonated molecular ions of a mixture of the NeuAc-M2 and NeuAc-GM3 classes. Using this approach, quantitative determination of NeuAc-GM3 d18:1-16:0 from rat adrenal gland was performed sing N-acetylneuraminic acid assay as a test control. We found 278±36 ng of this species in 1 mg of tissue (three replicate experiments). The procedure represents a senstive method for the quantitation of mionosialogangliosides and its capability to give molecular species information.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/rcm.1290051210
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  • 9
    Electronic Resource
    Electronic Resource
    Molecular reorientation and vibrational relaxation in dibromomethane (1984)
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 15 (1984), S. 152-155 
    Details
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The polarized and depolarized Raman spectra of the ν2 (CH2 bend) and ν3 (C—Br stretch) vibrations in dibromomethane have been studied as a function of temperature throughout the liquid range. Reorientational correlation times derived from the two modes were simllar in both magnitude and dependence on temperature. This result, together with other structural data, suggests that the rotational dynamics of this molecule in the liquid phase are quasi symmetric-top in character. Vibrational dephasing times calculated from the two lineshapes were also of the same magnitude. However, modulation times determined via the Kubo lineshpae formalism varied markedly between the vibrations. This provides evidence that vibrational dephasing of the bending and stretching modes are influenced by different intermolecular forces in the liquid.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jrs.1250150304
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