ISSN:
0749-1581
Keywords:
Thiadiazapentalene
;
15N NMR
;
Long-range 2D NMR
;
Inverse 2D
;
NMR
;
ESCA
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Reaction of 2-methyl-3-thiocyanatocrotonaldehyde with aniline hydrochloride and subsequent addition of dicyclohexylamine afforded a new 6a-thia(SIV)-1,6-diazapentalene. The presence of the N—S—N bond was verified through the N 1s and S 2p binding energies and the nitrogen-nitrogen coupling constant in the doubly 15N-labelled compound, prepared by using [15N]aniline hydrochloride.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260280507
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