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  • Polymer and Materials Science  (8)
  • Cell & Developmental Biology  (5)
  • 21.10.Pc  (2)
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  • 11
    Electronic Resource
    Electronic Resource
    Chemische und elektrochemische Reaktionen von Eisensulfid und Mangansulfid in sauren und neutralen Lösungen (1981)
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 275-281 
    Details
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Chemical and electrochemical reactions of iron sulfide and manganese sulfide in acid and neutral solutionsThe reactions which occur upon corrosion of massive iron sulfide and manganese specimens in perchloric acid and in neutral sodium chloride solution were elucidated by measurements of current-potential curves and by coulometric and analytical investigations on the processes. In acids the sulfides are dissolved by prevailing chemical reaction under evolution of H2S. Upon applying anodic overpotentials electrochemical reactions occur simultaneously, however, with such low velocity that the contribution to corrosion of the sulfides is insignificant. Upon applying cathodic overpotentials some hydrogen discharge is observed on iron sulfide but not on manganese sulfide.In 3% sodium chloride solution both sulfides corrode very slowly upon anodic polarization, forming elementary sulfur according to MeS = Me2+ + S + 2e- (Me = Fe or Mn). At high anodic potentials additional oxidation reactions occur in which three-valent iron and tetravalent manganese ions as well as sulfite and sulfate ions are formed.Iron sulfide and manganese sulfide inclusions can he isolated from steels only by electrochemical dissolution in neutral or weakly basic electrolytes, the potential during electrolysis must not be more positive than the corrosion potential of the sulfides.
    Notes: Durch Messen von Stromdichte-Potentialkurven und coulometrisch-analytische Untersuchungen wurden die Korrosionsreaktionen kompakter Eisensulfid- und Mangansulfidproben in Perchlorsäure, und in neutraler Natriumchlöridlösung aufgeklärt. In Säuren lösen sich beide Sulfide weitgehend chemisch unter H2S-Entwicklung. Daneben laufen bei anodischer Überspannung elektrochemische Reaktionen mit so geringer Geschwindigkeit ab, daß sie nur einen unbedeutenden Beitrag zur Korrosion des Eisensulfids und Mangansulfids liefern. Kathodisch werden am Eisensulfid Wasserstoffionen entladen. Diese Reaktion ist am Mangansulfid praktisch nicht feststellbar.In dreiprozentiger Natriumchlöridlosung korrodieren die beiden Sulfide bei anodischer Überspannung elektrochemisch sehr langsam unter Bildung elementaren Schwefels nach MeS = Me 2+ + S + 2e-(Me = Fe oder Mn). Im Bereich hoher anodischer Polarisation treten zusätzliche Oxydationsreaktionen auf, durch die dreiwertiges Eisen bzw. vierwertiges Mangan sowie Sulfit- und Sulfationen entstehen. Eisensulfid und Mangansulfid können aus Stahlen nur durch elektrochemisches Lösen der Stahlmatrix in neutralen oder schwach basischen Lösungen isoliert werden. Außerdem soll das Elektrolysepotential nicht positiver als das Ruhepotential dieser Sulfide sein.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/maco.19810320605
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    Paper (German National Licenses)
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  • 12
    Electronic Resource
    Electronic Resource
    Soldering external connections to thin film systems (1981)
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 3 (1981), S. 16-22 
    Details
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: External connections to thin film hybrid integrated circuits (HICs) by solder bonding have several advantages over those bonded by solid phase or thermocompression bonding. This paper reviews these advantages and discusses the parameters necessary for high strength, reliable solder joints to thin films. Dissolution of the soluble thin film(s) into solder limits the solder reflow times. Recent work has shown that dissolution rates of thin films in solder depend primarily on the degree of thin film heat treatment prior to soldering, substrate surface texture, and the method of thin film deposition. Auger in-depth profiling data show that alloy formation and internal oxidation reduces film dissolution during solder reflow. Metallographic sectioning and chemical analysis are used to identify weak solder bond interfaces which result from intermetallic formation. Tin from the solder diffuses rapidly and reacts with soluble metals such as gold, palladium and copper to form brittle intermetallics such as AuSn4, PdSn4 and Cu6Sn5. Intermetallic formation between the solder and the thin film systems of interest can affect joint strength and reliability.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/sia.740030108
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    Paper (German National Licenses)
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  • 13
    Electronic Resource
    Electronic Resource
    Das durch das enzym amylomaltase eingestellte gleichgewicht oligomerer amylosenHerrn Prof. Dr. W. KERN mit herzlichen Glückwünschen zum 60. Geburtstag gewidmet (1966)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 92 (1966), S. 91-104 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: In the series glucose G, maltose G2, maltotriose G3 etc. the equilibria: 2 G2 = G3 + G (K1), G3 + G2 = G4 + G (K2) etc. are specifically catalysed by the enzyme amylomaltase. The equilibrated mixtures are analysed by chromatography and the equilibrium constants K1, K2 etc. are calculated. They rise from the value K1 = 0,9 asymptotically to a limiting value of ca. 1,05. Enthalpy, Entropy and free enthalpy of the reaction are (excepted the frist step) as expected nearly 0. The enzyme amylomaltase, as isolated from Escherichia coli ML (from Institute Pasteur, Paris) has a molecular weight of nearly 130 000 and a turnover of nearly 11 000 moles maltose per minute.
    Notes: In der Reihe Glucose G, Maltose G2, Maltotriose G3 usw. stellt Amylomaltase die Gleichgewichte: 2 G2 = G3 + G (K1), G3 + G2 = G4 + G (K2) usw. ein. Die Gleichgewichtsgemische werden chromatographisch analysiert und daraus die Gleichgewichtskonstanten K1, K2 usw. berechnet. Diese steigen vom Wert K1 = 0,9 ab bis zu einem Grenzwert von etwa 1,05 asymptotisch an. Enthalpie, Entropie und freie Enthalpie liegen, außer für den ersten Reaktionsschritt (K1), wie zu erwarten nahe bei 0. Das aus Escherichia coli (Stamm ML aus dem Institut Pasteur) isolierte Enzym Amylomaltase hat ein Molekulargewicht von etwa 130 000 und eine darauf bezogen Wechselahle von etwa 11 000 Mol Maltose pro Min.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1966.020920106
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    Paper (German National Licenses)
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  • 14
    Electronic Resource
    Electronic Resource
    Diacylglycerols and PMA are particularly effective stimulators of fluid pinocytosis in human neutrophils (1990)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Cellular Physiology 145 (1990), S. 465-471 
    Details
    ISSN: 0021-9541
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: Diacylglycerols (OAG, diC8) and PMA were found to stimulate fluid pinocytosis (net uptake of FITC-dextran) to a far greater extent than other neutrophil activators, such as the chemotactic agents fNLPNTL and LTB4, the microtubule disassembling agents colchicine and nocodazole, the kinase inhibitor H-7, or D2O. OAG and diC8 produce a dose-dependent increase in the uptake of FITC-dextran, which is up to about 25- to 30-fold the control value of unstimulated neutrophils. The protein kinase inhibitor H-7 alone had a small stimulating effect on the net uptake, and it failed to inhibit stimulation of fluid pinocytosis by PMA, OAG, and diC8. Also, the protein kinase inhibitor staurosporine failed to inhibit fluid pinocytosis stimulated by OAG, diC8, and PMA. Stimulated fluid pinocytosis and vacuolization in response to PMA or diacylglycerols is associated with surface ruffling of neutrophils. Pinocytosis as well as surface ruffling stimulated by PMA, OAG, diC8, or diC10 are suppressed in the presence of cytochalasin D. The results suggest that diacylglycerols may be instrumental in transducing the signal for stimulated pinocytosis and that the surface movements induced by diacylglycerols, and PMA may be instrumental in fluid pinocytosis.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jcp.1041450311
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    Paper (German National Licenses)
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  • 15
    Electronic Resource
    Electronic Resource
    Selective effects of the PKC inhibitors Ro 31-8220 and CGP 41 251 on PMN locomotion, cell polarity, and pinocytosis (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Cellular Physiology 161 (1994), S. 526-536 
    Details
    ISSN: 0021-9541
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: Using two newly synthesized inhibitors, Ro 31-8220 and CGP 41 251, of protein kinase C (PKC), we analyzed: (1) how distinct PMN functions (shape changes, locomotion, pinocytosis) are regulated, and (2) the role of protein phosphorylation and PKC in this process. We were able to transform: (1) resting PMNs into locomoting cells using fNLPNTL, (2) locomoting cells into non-locomoting highly pinocytic cells using PMA, and (3) PMA-stimulated cells showing marked pinocytosis into locomoting or into resting cells using Ro 31-8220. It is thus possible to selectively manipulate PMN function (resting state, locomotion, marked pinocytosis), indicating that there are different regulatory pathways. It was not possible to induce locomotion and marked pinocytosis simultaneously, indicating crosstalk between pathways. Ro 31-8220 inhibited PMA-induced shape changes (nonpolar cells) and pinocytosis, but not fNLPNTL-induced shape changes (polarity) and pinocytosis. At higher concentrations, Ro 31-8220 alone elicited cell polarity and chemokinesis, indicating that a constitutively active protein kinase is involved in maintaining the spherical shape of resting PMNs. Functional effects of another PKC inhibitor, CGP 41 251, on neutrophil function were strikingly different. CGP 41 251 selectively inhibited fNLPNTL-induced polarity and locomotion (but not colchicine or Ro 31-8220-induced polarity), and it failed to inhibit PMA-induced, stimulated pinocytosis and shape changes. Although the effects of Ro 31-8220 vs. CGP 41 251 on PMN function were strikingly different, the inhibition of profiles for constitutive and for fNLPNTL- or PMA-induced protein phosphorylation in intact PMNs showed only small differences, which could not yet be conclusively related to cell function. © 1994 Wiley-Liss, Inc.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jcp.1041610316
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    Paper (German National Licenses)
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