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  • Hematoporphyrin IX  (2)
  • 21H, 23H-Porphine  (1)
  • Etioporphyrin  (1)
  • High-Performance TLC  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Reversed-phase high-performance thin-layer chromatography of hematoporphyrin and its nickel, copper and zinc complexes (1986)
    Springer
    Chromatographia 21 (1986), S. 509-512 
    Details
    ISSN: 1612-1112
    Keywords: Thin-layer chromatography ; Porphyrin ; Metalloporphyrins ; Hematoporphyrin IX
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The thin-layer chromatographic mobility of hematoporphyrin IX (Hp) and its metal complexes on octyl (C8)- or octadecyl (C18)-bonded silica gel plate is described. The mobility order for those compounds is regular on both kinds of plate with various compositions of methanol-phosphate buffer mixtures as the developing solvents; thus, Cu-complex 〈 Ni-complex 〈 Hp (free acid) 〈 Zn-complex. The combination of a C18-plate with an 85∶15 (vol/vol) mixture of methanol and phosphate buffer (pH 3) is recommended for the successful separation of these four compounds.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02310537
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    High-performance liquid chromatographic separation of hematoporphyrin and its nickel, copper and zinc complexes on octadecyl-bonded stationary phase (1986)
    Springer
    Chromatographia 22 (1986), S. 132-134 
    Details
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Porphyrin ; Metalloporphyrin ; Hematoporphyrin IX
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The feasibility of reversed-phase high-performance liquid chromatography for the separation of metal complexes of hematoporphyrin IX (Hp) is described. The retention order, Zn-complex〈Hp (free acid)〈 Ni-complex〈Cu-complex, is regular on an octadecylbonded stationary phase with different compositions of an aqueous methanol mobile phase. These four compounds can be successfully separated within about 8 min on a LiChrosorb RP-18 column (250×4-mm i.d.) with a 85:15 (vol/vol) mixture of methanol and phosphate buffer (pH 3) at a flow rate of 1 ml/min.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02257313
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    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    Non-aqueous, reversed-phase, high-performance, thin-layer chromatography and column liquid chromatography of metal complexes of porphine (1986)
    Springer
    Chromatographia 22 (1986), S. 160-164 
    Details
    ISSN: 1612-1112
    Keywords: Thin layer chromatography ; Column liquid chromatography ; 21H, 23H-Porphine ; Metalloporphyrin complexes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The chromatographic mobility of 21H, 23H-porphine and its Ni(II), Cu(II), Zn(II) and Pd(II) complexes were investigated by high-performance thin-layer chromatography on an octadecyl-bonded, silica gel plate with various polar organic solvents including alcohols, acetonitrile, dimethylsulfoxide and propylenecarbonate. The mobility generally decreases according to the central metal ion of the complex as follows: Zn(II)〉(free porphine)〉Ni(II)〉Pd(II)〉Cu(II). Methanol is a good choice of solvent for the separation of these metal porphine complexes. Successful separation of porphine and the four metal complexes is accomplished within 13 min on a LiChrosorb RP-18 column with methanol eluent.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02257319
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    Paper (German National Licenses)
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  • 4
    Electronic Resource
    Electronic Resource
    High-performance thin-layer chromatography of etioporphyrin and its vanadium (IV), nickel (II) and coper (II) complexes (1985)
    Springer
    Chromatographia 20 (1985), S. 417-420 
    Details
    ISSN: 1612-1112
    Keywords: High-Performance TLC ; Metal complexes ; Etioporphyrin
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The RF values were obtained for etioporphyrin I (H2Etio) and its vanadyl, nickel and copper complexes on cellulose, silica gel, and octyl-bonded silica HPTLC plates, with various organic solvents. The mobility of these compounds tends to increase in the following order: (1) on cellulose, VOEtio 〈 H2Etio 〈 CuEtio ≤ NiEtio; (2) on silica gel, H2Etio 〈 VOEtio 〈 NiEtio ≤ CuEtio; (3) on octyl-bonded silica, CuEtio 〈 NiEtio 〈 VOEtio and the apparent mobility of H2Etio relative to metal-Etio complexes depends on the developing solvent used. Complete separation of these four Etio compounds can be accomplished on an octyl-bonded silica plate with either methanol or acetone.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02265483
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    Paper (German National Licenses)
    Fulltext
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