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  • 1
    ISSN: 1434-601X
    Keywords: 27.30+t ; 21.10 Hw ; 21.60 Cs
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Theγ-decays of levels in26Mg have been investigated up to 12.5 MeV excitation energy by proton-γ-ray coincidence measurements in the23Na(α, pγ) reaction at 14.2 and 16 MeV bombarding energy. Lifetime-measurements, made with the Doppler-shift attenuation method, and proton-γ-ray angular-correlation measurements were performed at Eα=14.2 MeV. Many high-spin states were observed, among them levels at 6,978 (5+), 7,283(4−), 7,395(5+), 7,953(5−), 8,202(6+), 8,472(6+), 9,065(5), 9,112(6+), 9,169(6−), 9,383 (6+), 9,542(5), 9,829(7+), 9,989(6+) and 12,479(8+, 7−) keV excitation energy. The spectrum of positive-parity states and their electromagnetic properties are reproduced with good accuracy by shell-model calculations which employ a unifieds-d shell Hamiltonian and the unrestricted configuration space of the 0d 5/2 1s 1/2 0d 3/2 shell. Members of five inferred rotational bands, withK π=0+, 2+, 3+, 0+ and 3− have been observed up to at leastI=6. TheK π=2+ band shows strong anomalies of excitation energies andE2 transition rates near theI=6 state. The static intrinsic quadrupole moments calculated from the shell model wave functions indicate transitions from prolate to oblate deformation within theK π=2+ band and also the ground state band. The lowest lyingI π=4+ state appears to be “spherical” and cannot be associated with a rotational band.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 22 (1983), S. 475-479 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Anaphylactogenic, monohaptenic conjugates carrying a 2,4-dinitro-5-carboxyphenyl substituent as haptenic group and either one of two types of auxiliary groups essential for their anaphylactogenicity were studied. The “hydrocarbon auxiliary groups” require the presence of a hydrocarbon structure such as aliphatic chains of discrete length or planar rings such as provided by phenyl- or nicotinoyl residues and become particularly effective in conjunction with a carboxylate group. The benzylpenicilloyl group is an effective auxiliary structure, but the thiazolidine ring as such is not. It appears that the distance between haptenic and hydrocarbon auxiliary groups can be quite large. The “carbohydrate auxiliary group” becomes effective via a different mechanism. It requires disaccharide residues or two closely connected monosaccharides. Single monosaccharides are ineffective. A concept of interest with regard to drug allergy is the possibility that attachment of a single haptenic molecule to a glycoprotein constitutes an anaphylactogen.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 16 (1978), S. 1137-1145 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The equilibrium constant of the charge-transfer complex of styrene and fumarodinitrile was determined by ultraviolet and NMR measurements. Information about the role of the complex in the copolymerization of the two monomers could be obtained from copolymerization experiments at different monomer concentrations and temperatures. In addition, the influence of a second donor, anisole, was studied. The results show that in the copolymerization of styrene with fumarodinitrile addition of charge-transfer complexes has to be taken into account besides the addition of the free monomers.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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