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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 127 (1996), S. 397-415 
    ISSN: 1434-4475
    Keywords: Lithiated oximes ; Lithiated oxime ethers ; N-Benzylideneamines ; C=N-Electrophiles ; 5-Aminoisoxazolines
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Die Reaktion lithiierter Acetophenonoxime bzw. ihrer O-Methylether mit Benzylidenaminen führt zu (1,3-Diphenyl-3-hydroxyimino-1-propyl)-aminen bzw. zu deren O-Methylderivaten. Diese Verbindungen sind Vorstufen für 1,3-Diphenylpropan-1,3-diamine.
    Notes: Summary The reaction of lithiated acetophenone oximes and their O-methyl ethers with benzylideneamines affords (1,3-diphenyl-3-hydroxyimino-1-propyl)-amines or their O-methyl derivatives, respectively, which are precursors of 1,3-diphenylpropane-1,3-diamines.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1434-6079
    Keywords: 32.70.-n ; 34.20.-b
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Excitation spectra of the transitions 2P ΛA → 3D Λ and 2P Λ → 3PΛ in LiHe and LiNe collision molecules have been measured in the spectral range 15800–17600 cm−1 about the atomic Li2P → 3D line by means of two-step laser excitation. Rainbow satellite bands are observed and have been identified as due to maxima in the difference potentials 2PΣ-3DΣ, 2PΠ-3DΣ and 2PΛ-3PΣ, that are turn related to potential barriers in the upper 3PΣ and 3DΣ states. For identification of the satellites as well as understanding origin and shape of the potential barriers, approximate calculations were performed of interaction energies and dipole transition moments, that are based on the Fermi-Omont treatment of higher excited alkali-rare gas interaction. The satellite bands were analysed by means of semiclassical Uniform-Franck-Condon calculations of the spectra to yield values for characteristic parameters of the potential barriers. The results for position and height of the 3DΣ barrier are found to disagree more or less with values from different theoretical calculations.
    Type of Medium: Electronic Resource
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