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  • 71.20  (1)
  • 78.40. - q  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 62 (1996), S. 19-27 
    ISSN: 1432-0630
    Keywords: 42.25.Fx ; 78.20.Dj ; 78.40. - q ; 82.70.Dd
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Formation of particle aggregates of arbitrary size and shape by lumping of small particles yields extinction and scattering of light that differ from those of isolated particles. The aggregation process can be followed from extinction and angle-resolved light scattering measurements. Introducing new parameters in angular light scattering, systems containing only isolated clusters were efficiently distinguished from cluster-aggregate systems. This was achieved by evaluation of the measured data in forward and backward scattering direction and at a scattering angle of 90°, resulting in a distinct separation of isolated-cluster systems and cluster-aggregate systems. For measuring the angle-resolved light scattering by noble metal colloidal particle systems, a common photogoniometer setup had to be modified. Changes in scattering and extinction data were qualitatively described by a model that takes into account electromagnetic coupling among clusters in the aggregate.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 20 (1991), S. 377-379 
    ISSN: 1434-6079
    Keywords: 79.60 ; 71.20 ; 36.40
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We measured XPS and UPS spectra of gold clusters with 55 atoms, embedded in an electrically isolating phosphine matrix, and of gold-phosphine, from which the clusters were chemically derived. Compared to the spectra of bulk gold the valence band spectrum and the core level spectra of the clusters showed shifts of the peaks and the fermi level to higher binding energies. The shift of the peaks could qualitatively be interpreted by a final state effect. We succeeded in a separation of bulk and surface contributions to the core level spectra and in a reasonable quantitative analysis of the valence band spectrum of the clusters. The Au 4f core level spectrum of gold-phosphine showed two peaks at 1.5 eV higher binding energies than the corresponding peaks of the clusters.
    Type of Medium: Electronic Resource
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