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  • Chemistry  (12)
  • Cell & Developmental Biology  (2)
  • 82.65.Jv  (1)
  • ACRT  (1)
  • 11
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 24 (1996), S. 821-829 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Ammonia plasmas produced in a helical resonator have been investigated using an energy-selective mass spectrometer and an r.f.-compensated Langmuir probe. The effect of processing parameters on the plasma composition and ion energy distributions have been examined. The dominant ion present in the plasma was found to be NH4+, which varied in concentration between 95% and 65%, dependent upon operating conditions. Similarly, by relatively small variations in processing parameters it was possible to vary the NH3+ ion concentration between 1.7 and 31%. In addition, no radicals (NH2•, NH• or N•) were detected using threshold ionization mass spectroscopy. Polytetrafluoroethylene (PTFE) samples were treated under a variety of different plasma conditions, and the chemical changes induced were studied by in situ XPS.Defluorination was observed to be greater under conditions that yield low ion energies or high concentrations of NH3+ ions. Conditions giving rise to significant concentrations of NH3+ ions result in the production of NH3+F- groups. Evidence is provided suggesting that NH3+ ions are much more reactive with PTFE surfaces than NH4+ ions.
    Additional Material: 17 Ill.
    Type of Medium: Electronic Resource
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  • 12
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A low-power plasma treatment has been adapted to work on a pilot plant scale to continuously treat a tow of carbon fibres. This treatment successfully increases fibre-resin adhesion to levels comparable if not higher than those obtained by commercial electrochemical treatments. One advantage is that the plasma treatment does not appear to affect the tensile properties of the fibre, unlike the electrochemical oxidation.We have also shown that the chemical groups introduced during air plasma treatment play a significant role in fibre-resin adhesion whereas those introduced by electrochemical oxidation do not. A possible explanation for this is that plasma treatments introduce chemical groups onto the immediate surface of the fibres that have the potential to react with the resin, whereas electrochemical oxidation occurs predominantly at the edge sites and proceeds into the sublayers of the fibre. The vast majority of the functional groups are therefore inaccessible to the resin. This type of plasma treatment, however, is unlikely to remove all of the weakly bound layers as in the case of electrochemical treatment because the sputtering capability of the plasma is very low.The fact that these conclusions can be drawn from both the single-fibre fragmentation test and the short-beam shear test is encouraging and goes to prove that both these tests are suitable for looking at trends in fibre-resin adhesion.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 13
    ISSN: 0095-9898
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Journal of Chemical Technology AND Biotechnology 59 (1994), S. 115-115 
    ISSN: 0268-2575
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 15
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Biochemical and Microbiological Technology and Engineering 1 (1959), S. 77-98 
    ISSN: 0368-1467
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Fractions of markedly different protein contents may be obtained by air-classifying flour (in the sub-sieve range) at cut sizes of about 17 and 35 μ respectively. Of these fractions, the fine, 1 (of high protein content), contains fragments of interstitial endosperm protein and small starch granules; the intermediate, 2 (low protein), mainly large starch granules; the coarse, 3, fragments of endosperm cells. The yields and protein contents of the fractions vary with different wheats; the yields of 1 and 2 may be greatly increased through suitably grinding the flour after milling.In general, 1 may be used for raising the protein content of flours deficient in protein to a level suitable for bread-making. The amount of 1 required depends on its protein contents and on whether it came from a hard or soft wheat, the hard wheat fraction having better bread-making qualities. The resulting variation in the proportion of 1 required in the blend causes variation in the proportion of other particulate materials introduced with 1, in which they have become concentrated during the air classification. These include diastatically active agents and finely divided discolouring matter; the level of the former reached in the blend greatly affects its bread-making value. Pre-grinding of the flour may be helpful in this respect.When chlorinated, 2 is potentially useful for making light-structured cakes, but hard English wheats have mainly given less satisfactory results than soft. Under certain conditions, 3, with or without 2, may be better for biscuit-making than the parent flour.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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