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  • Chemistry  (28)
  • Polymer coating  (3)
  • Computational Chemistry and Molecular Modeling  (2)
  • Acute Pancreatitis-Complications  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Langenbeck's archives of surgery 328 (1971), S. 314-327 
    ISSN: 1435-2451
    Keywords: Pancreatitis ; Surgery ; Acute Pancreatitis ; Pancreatectomy ; Acute Pancreatitis-Complications
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Description / Table of Contents: Zusammenfassung Das Studium von 17 Fällen, bei denen eine Frühpankreatektomie durchgeführt wurde, bestimmt wie folgt unser therapeutisches Verhalten: Bei der akuten postoperativen Pankreatitis sind wir angesichts des schwerwiegenden Krankheitsverlaufes überzeugt von der Notwendigkeit einer frühzeitig durchzuführenden ausgedehnten Pankreatektomie. Bei der akuten primären Pankreatitis sind wir etwas zurückhaltender, da selbst bei offener Bauchhöhle das Schicksal gewisser Pankreaspartien nicht mit Sicherheit vorhergesagt werden kann. Dennoch bestimmen unsere im Vergleich mit den Literaturangaben günstigen persönlichen Erfahrungen mit der Pankreatektomie unser aktives chirurgisches Vorgehen bei der akuten nekrotisierenden hämorrhagischen Pankreatitis.
    Notes: Summary The study of 17 cases of acute pancreatitis, in whom early total or subtotal pancreatic resection were performed, has led to the following therapeutic principles: the serious nature of acute post-operative pancreatitis has convinced us of the necessity for early intervention and as extensive a resection as possible; 5 out of 6 patients were cured in this way. In case of acute primary pancreatitis we are more conservative since even at laparotomy it is difficult to foresee the fate of all parts of the pancreas. Nevertheless our relatively favorable results led us to intervene surgically if the signs and symptoms of pancreatitis do not show any improvement after 8 to 12 h. If acute, diffuse pancreatitis affects the whole organ subtotal pancreatectomy is performed. If the head of the pancreas is affected we confine ourselves to the removal of necroses. Duodenopancreatectomy does not seem justified in the acute phase; only 1 out of 3 patients survived this procedure.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Anion-exchange stationary phases ; Polymer coating ; Cross-linking
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary PHEB=POLY(2-hydroxy, 3N-ethylenediamino)butadiene has been synthesized. This unsaturated pre-polymer can be immobilized on different, preferably inorganic supports of suitable porosity such as silica or alumina by cross-linking. Weak anion-exchange phase are obtained. Such phases do not have the disadvantages of organic polymeric phases, regarding pressure stability and swelling by solvent influence. The ion-exchange capacity and the retentivity of IE-separations can deliberately be varied via the thickness of the cross-linked polymer layer. Alumina can also be coated with PHEB applying the same cross-linking procedure. Such phases exhibit an exceptional chemical stability even when operated with mobile phases at very high pH-values. Separations of excellent selectivity are achieved for inorganic anions, as well as with mixtures of aliphatic and aromatic free acids also including hydroxy- (mono- or poly)carboxylic acids.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie in unserer Zeit 24 (1990), S. 206-214 
    ISSN: 0009-2851
    Keywords: Chemistry ; Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 25 (1988), S. 265-271 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Chiral phases ; Polymer coating ; Quinine substituted polysiloxanes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Stationary phases for chiral separations have been synthesized by chemical modification of porous small particle silica using new procedures of fixation of the chiral moiety. So called pre-polymers of the methylpolysiloxane polysiloxane type are immobilized on silica surfaces by different procedures. These pre-polymers are substituted by chiral groups. Their synthesis is done externally i.e. not in-situ on the support surface. The immobilization on the silica surface is achieved by crosslinking and/or by chemical bonding. Anchor groups within the pre-polymer (e.g. SiH) as well as on the silica surface (SiOH) give rise to the chemical bonding therewith. Chiral phases with quinine as the chiral moiety were obtained which show high separation efficiency as well as chemical stability, in addition to the enantiomeric selectivity required for the separation of certain types of aliphatic and aromatic alcohols.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 23 (1987), S. 465-472 
    ISSN: 1612-1112
    Keywords: Cation-exchange LC ; Polymer coating ; Silica-based stationary phase
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The procedure of polymer coating of preferably inorganic porous particle support materials for LC has been applied to the preparation of a new type of weak cationexchange phases. A special copolymer of butadiene and maleic acid could be immobilized on silica by cross-linking effected with radical starters such as peroxides or γ-radiation. The chromatographic properties of such materials proved to be excellent regarding efficiency, ion-exchange capacity and selectivity, as well as chemical stability also in comparison to other, commercially available, materials. Test measurements were successfully performed with ionic or ionizable inorganic and organic solutes over the entire applicable pH-range of the mobile phase which also contained organic modifiers. A special feature of the new type of cation-exchange phase is the minor contribution of hydrophobic (lipophilic) interaction to the retention mechanism besides the actual ion-exchange process.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 6 (1975), S. 52-54 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Experimental Investigation of the Statistical Size-Effect in Fatigue Tests with Unnotched Specimens.In constant-load-fatigue-tests with unnotched specimens of different lengths, the statistical effect of specimen's size in probability of lifetime to fracture was determined.
    Notes: Im einstufigen Dauerschwingversuch an ungekerbten Proben mit unterschiedlichen Meßlängen konnte der statistische Einfluß der Probengröße auf deren Bruchwahrscheinlichkeit experimentell nachgewiesen werden.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 11 (1988), S. 191-197 
    ISSN: 0935-6304
    Keywords: Capillary SFC ; Instrumentation ; Sampling techniques ; Restrictors ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Different designs of injection and restriction devices for capillary supercritical fluid chromatography (SFC) have been investigated with respect to their practical applicability and usefulness for reproducible and accurate qualitative and quantitative analyses. In combination with a self-made instrument a fast switching valve is preferable as an injection device compared to a split-injector, and an integral restrictor made from the end of the fused silica (FS) separation column was superior to a linear restrictor made by coupling a small diameter FS-column to the separation column.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 64 (1992), S. 793-793 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 69 (1997), S. 1229-1230 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 68 (1996), S. 1088-1088 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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