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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 119 (1988), S. 889-901 
    ISSN: 1434-4475
    Keywords: Adsorption ; Heterogeneous adsorbents, Micropore-size distributions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Es wird eine theoretische Beschreibung der Gasadsorption an mikroporösen Feststoffen mitGaußscher Verteilung der Porengrößen präsentiert. Diese Beschreibung beinhaltet Gleichungen für die Gesamtadsorptions-Isotherme, die Adsorptionspotential-Verteilung, die differentielle molare Enthalpie und die differentielle molare Entropie der Adsorption. Es wird angenommen, daß eine vereinfachteGauß-Verteilung der Mikroporen die strukturelle Heterogenität wiedergibt, währenddessen eine Adsorptionspotential-Verteilung zur Darstellung der energetischen Heterogenität der Mikroporen verwendet wird.
    Notes: Abstract This paper presents a theoretical description of gas adsorption on microporous solids withGaussian micropore-size distributions. This description comprises equations for the overall adsorption isotherm, the adsorption potential distribution, the differential molar enthalpy, and the differential molar entropy of adsorption. The truncatedGaussian micropore-size distribution is assumed to represent the structural heterogeneity of the micropores, whereas the adsorption potential distribution is used to characterize the energetic heterogeneity of these micropores.
    Type of Medium: Electronic Resource
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