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  • Air pollution  (1)
  • Organic Chemistry  (1)
  • 1
    ISSN: 1432-0738
    Keywords: Engine exhaust ; Oxygen activation ; Air pollution ; Catalytic converter
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract Aqueous solutions of engine exhaust condensation products were derived from cars powered by diesel or four-stroke gasoline engines (with and without three-way catalytic converter). The cars were operated on a static test platform. Samples of the different exhaust solutions accumulated in a Grimmer-type distillation trap (VDI 3872) during standard test programs (Federal Test Procedure) were incubated with important biomolecules. As indicators of reactive oxygen species or oxidative destruction, ascorbic acid, cysteine, glutathione, serum albumin, the enzymes glycerinaldehyde phosphate dehydrogenase and xanthine oxidase, and the oxygen free-radical indicator keto-methylthiobutyrate were used. During and after the incubations, oxygen activation (consumption) and oxidative destruction were determined. Comparison of the oxidative activities of the different types of exhaust condensates clearly showed that the exhaust condensate derived from the four-stroke car equipped with a three-way catalytic converter exhibited by far the lowest oxidative and destructive power.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0170-2041
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Pteridines, LXXXIII. - Isolation and Structural Elucidation of Euglenapterin from Euglena gracilisThree new unusual pteridine derivatives have been isolated from Euglena gracilis. Their structures were elucidated by spectroscopic means and by synthesis as N2,N2-dimethyl-6-(L-threo-1,2,3-trihydroxypropyl)pterin (9) and its 3′-monophosphate 16 and 2′,3′-cyclophosphate 15. The 2-dimethylamino group was found for the first time in a naturally occurring pterin.
    Notes: Aus Euglena gracilis werden drei neue ungewöhnliche Pteridine isoliert und ihre Strukturen als N2,N2-Dimethyl-6-(L-threo-1,2,3-trihydroxypropyl)pterin (9) sowie dessen 3′-Monophosphat 16 und 2′,3′-Cyclophosphat 15 durch spektroskopische Methoden und Synthese gesichert. Die 2-Dimethylamino-Funktion wurde damit erstmals in einem natürlichen Pterin nachgewiesen.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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