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  • Analytical Chemistry and Spectroscopy  (13)
  • Chemical Engineering  (9)
  • Biochemistry  (3)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 689-693 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 1181-1187 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Particle-to-gas heat transfer coefficients were determined in packed and fluidized beds with large diameter particles and high mass velocities using the cyclic temperature method.Experimental results for packed beds were satisfactorily correlated within 10% deviation as εjh vs. NRe and were found to compare favorably with results of other experimenters obtained with much lower mass velocities and larger particles. The particle-to-gas heat transfer coefficient varied as G0.60 for the steel spheres vs. G0.66 for the tungsten spheres, and as Dp-0.44.Heat transfer coefficients obtained at minimum fluidization were in good agreement with those obtained with packed beds. As the mass velocity was increased above that required for minimum fluidization, heat transfer coefficients remained essentially constant.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 260-265 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The point of inversion of a water-in-oil type of dispersion to an oil-in-water type is investigated for several water-oil systems by studying the volume ratios of the phases in relation to their physical properties. The point of inversion for each system of an immiscible organic liquid and water and organic liquid mixture and water is obtained by varying the phase-volume ratios and determining the type of dispersion after complete mixing. The effects of temprature, interfacial tension, and density are found to have no correlation generally applicable to the systems studied. A volume-viscosity relationship is found to exist within limits. This correlation is that the phase-volume ratio at the point of inversion is equal to the square root of the ratio of teh viscosities of the respective phases at the interface. The theoretical aspects of this relationship are studied along with its limitations.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 22 (1976), S. 691-695 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Comparison of solute concentrations at the outlet of a model dialyzer with values calculated from the appropriate convective diffusion equation yielded effective diffusion coefficients for mass transfer of sodium chloride in sherared suspensions of 37 to 74 μ spheres of a copolymer of styrene-divinylbenzene. Significant mass transfer augmentation was observed over that attributable to molecular diffusion, and the effective diffusivity increased with increasing concentration of suspension but remained relatively constant with respect to shear rate over the experimental range.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 34 (1994), S. 213-220 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A squeezing flow viscometer was developed to characterize the rheological properties of luorinated thermoplastics. The viscosities of CTFE (polychlorotrifluorethylene) and FEP (a copolymer of tetrafluoroethylene and hexafluoropropylene) were determined using the viscometer by assuming that the shear-rate dependent viscosity can be described by a power-law, a truncated power-law, or an Ellis model. The results were in agreement with the viscosities measured with steady shear cone-and-plate viscometry and oscillatory cone-and-plate rheometry. Although the squeezing flow behavior of the polymers can be well explained by the purely viscous models, the power-law model is valid only for a limited range of shear-rates whereas the other two models are useful over a relatively wide range.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 22 (1982), S. 354-357 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Accelerated-stress life-testing involves testing of a material or system at a series of stresses higher than that which is normally seen in service. An estimate of the service life is then obtained by extrapolating the failure time vs stress relationship to use stress. A common problem with this methodology is that a change in failure mechanism may occur if stresses become too high. When this occurs, the data above and below the failure mode transition point are generally treated separately. This paper discusses a model that allows for a change in failure mechanism and characterizes the transition by a probability density function over stress. Advantages of the model are: it allows representation of all test data by a single equation; it allows probability statements to be made about the probability of failure of either failure mode; it allows optimal experiments to be designed; and it allows data in the area of the failure mode transition to contribute to the precision of the estimated service life.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 16 (1976), S. 252-256 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The possible reinforcing effects of six different types of filler particles on composites based on the thermoplastic polypropylene have been examined. It is found that significant increases in elastic modulus and tensile strength can be obtained by addition of ≥ 10 percent by volume of glass fibers. Ceramic whiskers, based on alumina and silicon carbide, also lead to increases in modulus but to decreases in strength and ductility. Additional measurements were made with composites prepared from two sizes of spherical glass beads and from carbon spheres. For the glass beads, an increase in modulus was obtained but strength and elongation to fracture decreased. Carbon spheres were ineffective as a reinforcing agent. The possible effects of nonuniform mixing, of size and shape of filler particles, and of surface coatings are discussed.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 4 (1990), S. 30-33 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The ion-trap mass spectrometer can be used to record mass and multi-stage tandem mass spectra (MSn) on small peptides. The compounds are ionized by Cs+ surface ionization, injected into the trap, mass selected, activated by collision, resulting in dissociation and mass-selectively ejected. Tandem mass spectrometric data on sub-fmol amounts of Gramicidin S are shown, along with tandem mass spectrometric and MSn data on two other peptides. The experiment is distinguished by its very high sensitivity and the high quality of sequence information obtained.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 11 (1984), S. 101-105 
    ISSN: 0306-042X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The copper salt of tenuazonic acid was studied by both positive and negative ion techniques. Fragmentation was elucidated with the aid of collision-induced dissociation/mass-analysed ion kinetic energy spectroscopy. During the course of the investigations, a homolog of tenuazonic acid was tentatively identified by using a combination of mass spectral techniques.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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