ISSN:
0030-4921
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Various N-nitrosamines were photolyzed in toluene solution in the temperature range -100°C to -30°C to yield dialkyl nitroxides. The nitrosamines studied were N-nitrosodimethylamine, N-nitrosodiethylamine, N-nitrosodipropylamine, N-nitrosodibutylamine and N-nitrosodicyclohexylamine. Subsequent nitroxide side products were also detected by ESR, and a mechanism for their formation is proposed. Temperature dependent hyperfine couplings of the methylene protons were observed for a few radicals of the type R1—CH2—NO·—R2.
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1270170213
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