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  • Analytical Chemistry and Spectroscopy  (3)
  • Thalassemia  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    European radiology 1 (1991), S. 81-84 
    ISSN: 1432-1084
    Keywords: Extramedullary Hematopoiesis ; Thalassemia ; Spine ; Liver ; Magnetic resonance imaging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract A 17 year old Iranian girl presented with thalassemia major, complicated by acute compression of the cauda equina caused by extramedullary haemopoiesis. The advantages of MRI in confirming the spinal space-occupying lesion and involvement of liver and pancreas are discussed in the context of treatment decision analysis and follow-up.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 25 (1994), S. 497-506 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Vibronically specific subrotational period lifetimes of the predissociated 22B2 state of NO2 vapour (250-235 nm) have been determined by spontaneous resonance Raman scattering polarization measurements. The lifetimes of the vibronic symmetric stretching, ν1′, (100), bending, ν2′, (101), and asymmetric stretching, ν3′, (002), overtone levels are 75 ± 10 fs, 2.5 ± 05 ps and 155 ± 15 fs respectively. When one quantum of bending (ν2,′) is excited in combination with one quantum of totally symmetric stretching (ν1′), the lifetime increases from 75 ± 10 to 125 ± 15 fs (110). The 22 B2 state electronic origin lifetime has been previously shown to be 42 ± 5 ps independent of angular momentum quantum numbers. These results are interpreted in terms of the shape of the potential energy surface intersections in the region and the results of earlier quantum yield measurements.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 21 (1990), S. 769-779 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Recent experimental and theoretical developments in spontaneous hyper-Raman spectroscopy (HRS) are reported. The scope of the general review of HRS presented summarizes the results of this non-linear scattering technique during the past 10 years. In particular, those aspects of HRS studies which allow novel observations as compared with other spectroscopic techniques are emphasized. HRS investigations of crystals, liquids and surface and electronic resonance enhancement are highlighted.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Raman scattering of two vibrational overtones of benzene is found to undergo strong preresonance enhancement as the excitation frequency approaches the 1B2u state, the lowest lying, forbidden electronic transition at 265 nm. These preresonance active modes are the first overtone of the 606 cm-1 e2g fundamental, which is responsible for the vibronically induced 1B2u intensity, and the first overtone of the 848 cm-1 e1g fundamental, an out-of-plane C—H bending mode. In order to treat this overtone preresonance Raman behavior theoretically, the molecular polarizability is consistently expanded to second order in nuclear displacements, and thus we consider all preresonance contributions of this order. The leading contributions of strictly dipole-forbidden electronic transitions to the scattering cross-section of overtones are exposed. Within this theoretical context it is seen how scattering cross-section for each of these resonance active overtones is derived from different sources. The preresonance scattering of the 606 cm-1 overtone results from the vibronic activity of this fundamental in the 1B2u transition. On the other hand, the 848 cm-1 overtone derives its 1B2u resonance activity from the change in its fundamental frequency (to 585 cm-1) in this excited electronic state. Furthermore, the 848 cm-1 overtone activity is built upon signifficant background preresonance contributions from other higher lying electronic transitions.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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